Thiostannate

{{Short description|Class of chemical compounds}} '''Sulfidostannates''', or '''thiostannates''' are chemical compounds containing anions composed of tin linked with sulfur. They can be considered as stannates with sulfur substituting for oxygen. Related compounds include the thiosilicates, and thiogermanates, and by varying the chalcogen: selenostannates, and tellurostannates. Oxothiostannates have oxygen in addition to sulfur.<ref>{{cite journal |last1=Benkada |first1=Assma |last2=Reinsch |first2=Helge |last3=Poschmann |first3=Michael |last4=Krahmer |first4=Jan |last5=Pienack |first5=Nicole |last6=Bensch |first6=Wolfgang |title=Synthesis and Characterization of a Rare Transition-Metal Oxothiostannate and Investigation of Its Photocatalytic Properties |journal=Inorganic Chemistry |date=18 February 2019 |volume=58 |issue=4 |pages=2354–2362 |doi=10.1021/acs.inorgchem.8b02773|pmid=30702285 |s2cid=73413851}}</ref> Thiostannates can be classed as chalcogenidometalates, thiometallates, chalcogenidotetrelates, thiotetrelates, and chalcogenidostannates. Tin is almost always in the +4 oxidation state in thiostannates, although a couple of mixed sulfides in the +2 state are known,

Some thiostannate minerals are known. In nature the tin can be partly replaced by arsenic, germanium, antimony or indium. Many thiostannate minerals contain copper, silver or lead. In the field of mineralogy, these compound can be termed '''sulfostannates''' or '''sulphostannates'''.

Different cluster anions are known: [SnS₄]^4–, [SnS₃]^2–, [Sn₂S₅]^2–, [Sn₂S₆]^4–, [Sn₂S₇]^6–, [Sn₂S₈]^2–, [Sn₃S₇]^2–, [Sn₄S₉]^2–, [Sn₅S₁₂]^4–, or [Sn₄S₁₀]^4–.<ref name="TP">{{Cite journal|last1=Lühmann|first1=Henning|last2=Näther|first2=Christian|last3=Jess|first3=Inke|last4=Bensch|first4=Wolfgang|date=2019-10-14|title=Synthesis, Crystal Structure, and Thermal Properties of Na₅[SnS₄]Cl·13H₂O|journal=Zeitschrift für anorganische und allgemeine Chemie|language=en|volume=645|issue=18–19|pages=1165–1170|doi=10.1002/zaac.201900169|issn=0044-2313|doi-access=free}}</ref>

The number of sulfur atoms coordinated around the tin atom is most commonly four. However there are also complexes with five or six sulfur atoms surrounding the tin. The behaviour for selenium and tellurium differs as only five selenium or four tellurium atoms can bind to a tin atom. The smaller germanium atom can only accommodate four sulfur atoms. For lead it is hard for it to be in the +4 oxidation state. The SnS_n polyhedrons can be standalone in strongly alkaline conditions, or at higher concentrations or less alkaline can condense together. Polyhedra shapes are tetrahedron for four, trigonal bipyramid for five, and octahedron for six sulfur atoms. The polyhedra can be connected at a vertex (corner), or at an edge. Where connected at an edge, four membered rings of -SnSSnS- with internal angles close to 90°.<ref name="shel">{{cite journal |last1=Sheldrick |first1=William S. |last2=Wachhold |first2=Michael |title=Chalcogenidometalates of the heavier Group 14 and 15 elements |journal=Coordination Chemistry Reviews |date=September 1998 |volume=176 |issue=1 |pages=211–322 |doi=10.1016/s0010-8545(98)00120-9}}</ref> [Sn₂S₇]^6– is corner bridged. Tetrahedra linked by at the corner by a disulfur bridge are unknown.<ref name="shel"/>

Sn₁₀O₄S₂₀^8- is a supertetrahedron made from 1, 3 and 6 tin atoms connected by oxygen on the interior and sulfur on the surface.<ref name="shel"/>

For anions with formula Sn_xS_y the condensation ratio c is given by {{frac|x|y}}. It can vary from {{frac|1|4}} to just below {{half}}.<ref name="shel"/>

== Synthesis == The first human production of a thiostannate heated tin oxide with sodium carbonate and sulfur:<ref name="FR">{{Cite journal|last1=Hilbert|first1=Jessica|last2=Näther|first2=Christian|last3=Bensch|first3=Wolfgang|date=2017-12-13|title=Fast Room Temperature Synthesis of the Thiostannate [Ni(2amp)₃]₂[Sn₂S₆]·9.5H₂O: Crystal Structure and Properties: Fast Room Temperature Synthesis of the Thiostannate [Ni(2amp)₃]₂[Sn₂S₆]·9.5H₂O: Crystal Structure and Properties|journal=Zeitschrift für anorganische und allgemeine Chemie|language=en|volume=643|issue=23|pages=1861–1866|doi=10.1002/zaac.201700193|doi-access=free}}</ref>

2SnO₂ + 2Na₂CO₃ + 9S → 2Na₂SnS₃ + 2CO₂ + 3SO₂

Transition metal complexes may be prepared by crystallisation from the ligand solvent.<ref name="FR"/>

Copper(II) is normally reduced by sulfide S^2- in thiostannates to copper(I).<ref name="CC">{{Cite journal|last1=Benkada|first1=Assma|last2=Reinsch|first2=Helge|last3=Bensch|first3=Wolfgang|date=2019-11-10|title=The First Thiostannate Compound with Copper(II) Synthesized Under Ambient Conditions: Crystal Structure, Electronic and Thermal Properties|journal=European Journal of Inorganic Chemistry |language=en|volume=2019|issue=41|pages=4427–4432|doi=10.1002/ejic.201900924|issn=1434-1948|doi-access=free}}</ref>

=== Anions === {|class="wikitable" !formula !name !coordination !dimensionality !description |- |[SnS₄]⁴⁻ | |4 |0 |tetrahedra |- |[Sn₂S₆]⁴⁻ |bis(μ-sulfido)-tetrathiolato-di-tin |4 |0 |edge shared |- |[Sn₃S₉]⁶⁻ |1,3,5,2,4,6-trithiatristanninane-2,2,4,4,6,6-hexakis(thiolate) |4 |0 |6 membered ring |- |[Sn₄S₁₀]^4- | |4 |0 |tetrameric adamantane-like : tetrahedron of tetrahedra, 6 bridging sulfur, 4 terminal sulfur |- |}

== Reactions == Some hydrates are unstable, where water reacts with the sulfide to make hydrogen sulfide gas.

== List == {|class="wikitable" !formula !system !space group !unit cell Å !volume !density !comment ! |- |Li₄SnS₄ |orthorhombic |''Pnma'' |a=13.812 b=7.962 c=6.370 | | | |<ref>{{Cite journal|last1=Kaib|first1=Thomas|last2=Haddadpour|first2=Sima|last3=Kapitein|first3=Manuel|last4=Bron|first4=Philipp|last5=Schröder|first5=Cornelia|last6=Eckert|first6=Hellmut|last7=Roling|first7=Bernhard|last8=Dehnen|first8=Stefanie|date=2012-06-12|title=New Lithium Chalcogenidotetrelates, LiChT: Synthesis and Characterization of the Li⁺ -Conducting Tetralithium ortho- Sulfidostannate Li₄SnS₄|url=https://pubs.acs.org/doi/10.1021/cm3011315|journal=Chemistry of Materials|language=en|volume=24|issue=11|pages=2211–2219|doi=10.1021/cm3011315|issn=0897-4756|url-access=subscription}}</ref> |- |[Li₈(H₂O)₂₉][Sn₁₀O₄S₂₀]'''·'''2H₂O |triclinic |''P''{{overbar|1}} |''a'' = 11.232, ''b'' = 13.097, ''c'' = 23.735, ''α'' = 102.73°, ''β'' = 90.43°, ''γ'' = 93.44°, ''Z'' = 2 |3399 | |oxothiostannate |<ref>{{Cite journal|last1=Kaib|first1=Thomas|last2=Kapitein|first2=Manuel|last3=Dehnen|first3=Stefanie|date=October 2011|title=Synthesis and Crystal Structure of [Li₈(H₂O)₂₉][Sn₁₀O₄S₂₀]·2H₂O|journal=Zeitschrift für anorganische und allgemeine Chemie|language=en|volume=637|issue=12|pages=1683–1686|doi=10.1002/zaac.201100268|doi-access=free}}</ref> |- |(NH₄)₄Sn₂S₆·3H₂O |orthorhombic |''P''4₁2₁2 |''a'' =8.56294 ''b'' =8.56294 ''c''= 22.7703 | | | |<ref name="PT">{{Cite journal|last1=Nørby|first1=Peter|last2=Overgaard|first2=Jacob|last3=Christensen|first3=Per S.|last4=Richter|first4=Bo|last5=Song|first5=Xin|last6=Dong|first6=Mingdong|last7=Han|first7=Anpan|last8=Skibsted|first8=Jørgen|last9=Iversen|first9=Bo B.|last10=Johnsen|first10=Simon|date=2014-08-12|title=(NH₄)₄Sn₂S₆·3H₂O: Crystal Structure, Thermal Decomposition, and Precursor for Textured Thin Film|url=https://pubs.acs.org/doi/10.1021/cm501681r|journal=Chemistry of Materials|language=en|volume=26|issue=15|pages=4494–4504|doi=10.1021/cm501681r|issn=0897-4756|url-access=subscription}}</ref> |- |(NH₄)₆Sn₃S₉·1.3H₂O |monoclinic |''C''2 |''a'' 16.9872 ''b'' 10.54777 ''c'' 21.0871 ''β'' 108.0389° |3592.6 |2.154 |colourless |<ref name=":21">{{Cite journal|last1=Nørby|first1=Peter|last2=Eikeland|first2=Espen|last3=Overgaard|first3=Jacob|last4=Johnsen|first4=Simon|last5=Iversen|first5=Bo B.|date=2015|title=Expanding the structural versatility of thiostannate( iv ) complexes|url=http://xlink.rsc.org/?DOI=C4CE02224F|journal=CrystEngComm|language=en|volume=17|issue=11|pages=2413–2420|doi=10.1039/C4CE02224F|bibcode=2015CEG....17.2413N |issn=1466-8033|url-access=subscription}}</ref> |- |[(CH₃)₃NH]₂Sn₃S₇ | | | | | | |<ref name="shel"/> |- |[(CH₃)₄N]₂Sn₃S₇'''·'''H₂O | | | | | | |<ref name="shel"/> |- |[(CH₃)₄N]₄Sn₄S₁₀ | | | | | | |<ref name="PT"/> |- |[(CH₃CH₂)₄N]₂Sn₃S₇ | | | | | | |<ref name="shel"/> |- |[(CH₃CH₂CH₂)₄N]₂Sn₄S₉ | | | | | | |<ref name="shel"/> |- |[(CH₃CH₂CH₂CH₂)₄N]₂Sn₄S₉ | | | | | | |<ref name="shel"/> |- |[(CH₃CH₂CH₂)₄N][(CH₃)₃NH]Sn₄S₉ | | | | | | |<ref name="shel"/> |- |(C₁₂H₂₅NH₃)₄Sn₂S₆ '''·'''2H₂O | | | | | | |<ref name="shel"/> |- |[dabcoH]₂Sn₃S₇ | | | | | | |<ref name="shel"/> |- |(Et₄N)₂Sn(S₄)₃ | | | | | | |<ref name="shel"/> |- |(Et₄N)₂Sn(S₄)₂(S₆) | | | | | | |<ref name="shel"/> |- |((CH₃C(NH₂)₂)₈Sn₂S₆SnS₄ |monoclinic |C 1 2/m 1 |a=23.7739 b=16.0647 c=11.8936 β=99.029 Z=4 |4486.1 |1.702 |colourless |<ref name=":21"/> |- |((CH₃)₂NH₂)(NH₄)SnS₃ dimethylammonium ammonium |orthorhombic |P2₁2₁2₁ |''a''=5.9393 ''b''=12.1816 ''c''=12.4709 Z=4 |902.26 |2.054 |colourless |<ref name=":21"/> |- |(DBNH)₂Sn₃S₆ DBN=1,5-diazabicyclo[4.3.0]non-7-ene | | | | | |Sn(II) and Sn(IV) |<ref name=":28">{{Cite journal|last1=Pienack|first1=Nicole|last2=Näther|first2=Christian|last3=Bensch|first3=Wolfgang|date=March 2009|title=Solvothermal Syntheses of Two New Thiostannates and an In-Situ Energy Dispersive X-ray Scattering Study of Their Formation|journal=European Journal of Inorganic Chemistry|language=en|volume=2009|issue=7|pages=937–946|doi=10.1002/ejic.200801084|doi-access=free}}</ref> |- |(1AEP)₂Sn₃S₇ 1AEP = 1-(2-aminoethyl) piperidine |orthorhombic |P2₁2₁2₁ |a=13.2299 b= 22.2673 c=9.0772 Z=4 |2674.1 | |pale yellow |<ref>{{Cite journal|last1=Filsø|first1=Mette Ø.|last2=Chaaban|first2=Iman|last3=Al Shehabi|first3=Amer|last4=Skibsted|first4=Jørgen|last5=Lock|first5=Nina|date=2017-10-01|title=The structure-directing amine changes everything: structures and optical properties of two-dimensional thiostannates|url=https://onlinelibrary.wiley.com/doi/10.1107/S2052520617010630|journal=Acta Crystallographica Section B|volume=73|issue=5|pages=931–940|doi=10.1107/S2052520617010630|pmid=28980999|bibcode=2017AcCrB..73..931F |issn=2052-5206|url-access=subscription}}</ref> |- |SnS₂·''en'' |monoclinic |''C''2/''c'' |''a'' 15.317 ''b'' 10.443 ''c'' 12.754, ''β'' 93.62° | | | |<ref name="SM">{{Cite journal|last1=Pada Nayek|first1=Hari|last2=Lin|first2=Zhien|last3=Dehnen|first3=Stefanie|date=October 2009|title=Solvent-modified SiS₂ -type SnS₂: Synthesis, Crystal Structures and Properties of ^{<big>∞</big>}[SnS₂·en] and [enH]⁴[Sn₂S₆]·en|url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.200900157|journal=Zeitschrift für anorganische und allgemeine Chemie|language=en|volume=635|issue=12|pages=1737–1740|doi=10.1002/zaac.200900157|url-access=subscription}}</ref> |- |[''en''H]₄[Sn₂S₆]·''en'' |triclinic |''P''{{overbar|1}} |''a'' 9.8770 ''b'' 9.9340 ''c'' 15.4230, ''α'' 72.630° ''β'' 86.220° ''γ'' 81.380° | | | |<ref name="SM"/> |- |Na₂SnS₃ | |''R''{{overbar|3}}''m'' |a=3.834 c=19.876 Z=2 |253 |3.43 | |<ref name="FR"/><ref name="ES">{{Cite journal|last1=Olivier-Fourcade|first1=J.|last2=Jumas|first2=J.C.|last3=Ribes|first3=M.|last4=Philippot|first4=E.|last5=Maurin|first5=M.|date=January 1978|title=Evolution structurale et nature des liaisons dans la série des composés soufrés du silicium, du germanium, et de l'étain|url=https://linkinghub.elsevier.com/retrieve/pii/0022459678900622|journal=Journal of Solid State Chemistry|language=fr|volume=23|issue=1–2|pages=155–176|doi=10.1016/0022-4596(78)90062-2|bibcode=1978JSSCh..23..155O|url-access=subscription}}</ref> |- |Na₄SnS₄ |tetragonal |''P''{{overbar|4}}2''1c'' |a=7.837 c=6.950 |427 |2.64 | |<ref name="ES"/> |- |Na₄Sn₂S₆ | | | | | | |<ref name="shel"/> |- |Na₄Sn₂S₆'''·'''14H₂O |triclinic |''P''{{overbar|1}} |a=10.114 b=7.027 c=9.801 α=108.30 β=92.18 γ=91.11 Z=1 |663 |1.95 | |<ref name="TP"/> |- |Na₄SnS₄'''·'''14H₂O |monoclinic |''C''2/''c'' |a=8.622 b=23.534 c=11.347 ''β''=110.53 Z=4 |2156 |1.82 | |<ref name="ES"/> |- |Na₄Sn₃S₈ | | | | | | |<ref name="shel"/> |- |Na₅[SnS₄]Cl'''·'''13H₂O |monoclinic |''P''2₁/''m'' |a=8.4335 b=11.4958 c=11.5609 ''β''=91.066 Z=2 |1120.63 |1.872 | |<ref name="TP"/> |- |Na₄Sn₂S₆·5H₂O | | | | | | |<ref name="shel"/> |- |Na₆Sn₂S₇ | |''C''2/''c'' |a=9.395 b=10.719 c=15.671 β=109.97 Z=4 |1483 |2.69 | |<ref name="ES"/> |- |Mg₂SnS₄ |orthorhombic |''Pnma'' |a=12.93 b=7.52 c=6.16 Z=4 |599 |3.28 | |<ref name="ES"/> |- |Na₂MgSnS₄ | |''R''{{overbar|3}}''m'' |''a'' 3.7496 ''b'' 3.7496 ''c'' 19.9130 | | | |<ref>{{Cite journal|last1=Heppke|first1=Eva M.|last2=Lerch|first2=Martin|date=2020-09-25|title=Na₂MgSnS₄ – a new member of the A^I₂B^IIC_IVX₄ family of compounds|url=https://www.degruyter.com/document/doi/10.1515/znb-2020-0102/html|journal=Zeitschrift für Naturforschung B|language=en|volume=75|issue=8|pages=721–726|doi=10.1515/znb-2020-0102|s2cid=222005297|issn=1865-7117|url-access=subscription}}</ref> |- |(Ph₄P)₂Sn(S₄)₃ | | | | | | |<ref name="shel"/> |- |K₂SnS₃ '''·'''2H₂O | | | | | | |<ref name="shel"/> |- |K₂SnS₃'''·'''2H₂O |orthorhombic |''Pnma'' |a=6.429 b=15.621 c=10.569 Z=4 |1061 |2.06 | |<ref name="ES"/> |- |K₂Sn₂S₅ | | | | | | |<ref name="shel"/> |- |K₂Sn₃S₇ '''·'''H₂O | | | | | | |<ref name="shel"/> |- |[K₄(H₂O)₄][SnS₄] | | | | | | |<ref name="NH">{{Cite journal|last1=Ruzin|first1=Eugen|last2=Jakobi|first2=Stephan|last3=Dehnen|first3=Stefanie|date=June 2008|title=Syntheses, Structures and Reactivity of Novel Hydrates of ortho-Sulfidostannte Salts|url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.200800004|journal=Zeitschrift für anorganische und allgemeine Chemie|language=de|volume=634|issue=6–7|pages=995–1001|doi=10.1002/zaac.200800004|url-access=subscription}}</ref> |- |Ca₂SnS₄ |orthorhombic |''Pnma'' |a=13.74 b=8.23 c=6.44 Z=4 |728 |2.99 | |<ref name="ES"/> |- |[H₂tepa][V^III(tepa)(μ-Sn₂Q₆)]₂ |orthorhombic |''Abm''2 |''a'' =7.7486 ''b'' =40.410 ''c'' =16.745 | | | |<ref name="DV">{{Cite journal|last1=Chen|first1=Yao|last2=Liu|first2=Xing|last3=Zhou|first3=Jian|last4=Zou|first4=Hua-hong|last5=Xiang|first5=Bin|date=2021-02-15|title=One-Dimensional Vanadium(III) Chalcogenidostannates Incorporating [V(tepa)] 3+ Complexes as Bridging Groups|url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c03484|journal=Inorganic 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L. |author2=Guo, G. C. |author3=Liu, B. |author4=Wu, A. Q. |author5=Huang, J. S.}}</ref> |- |[Mn(en)₂]₂(μ-en)[Sn₂S₆] |triclinic | |a=9.0017 b=9.7735 c=10.8421 ''α''=60.38° ''β''=67.23° ''γ''=70.25° |752.38 | | |<ref name="DV"/> |- |[Mn(dien)₂]₂Sn₂S₆ |monoclinic |''P''2₁/''c'' |a=12.48 12, b= 9.3760, c=17.7617, β=121.752°, Z=2, |1767.5 |1.789 | |<ref name=":5"/> |- |[Mn(tren)]₂Sn₂S₆ |triclinic |''P''{{overbar|1}} |''a'' 7.653 ''b'' 8.088 ''c'' 12.200, ''α'' 97.27° ''β'' 104.06° ''γ'' 108.80° Z=1 |676.0 |2.044 |yellow |<ref name="CC"/><ref name="MS">{{Cite journal|last1=Han|first1=Jing-yu|last2=Liu|first2=Yun|last3=Lu|first3=Jia-lin|last4=Tang|first4=Chun-ying|last5=Shen|first5=Ya-li|last6=Zhang|first6=Yong|last7=Jia|first7=Ding-xian|date=July 2015|title=Methanolothermal Syntheses, Crystal Structures and Optical Properties of Binuclear Transition Metal Complexes Involving the Bidentate S-Donor Ligand μ-Sn₂S₆|url=http://link.springer.com/10.1007/s10870-015-0601-3|journal=Journal of Chemical Crystallography|language=en|volume=45|issue=7|pages=355–362|doi=10.1007/s10870-015-0601-3|s2cid=93060529|issn=1074-1542|url-access=subscription}}</ref> |- |[Mn(tren)(H₂O)][Mn(baen)]₃Mn₄Sn₆S₂₀∙9H₂O |orthorhombic |''P''2₁3 |''a'' =21.404 ''b'' =21.404 ''c''= 21.404 | | |super tetrahedron |<ref>{{Cite journal|last1=Han|first1=Jingyu|last2=Li|first2=Shufen|last3=Zhang|first3=Limei|last4=Zheng|first4=Wei|last5=Jiang|first5=Wenqing|last6=Jia|first6=Dingxian|date=July 2018|title=T3 supertetrahedral cluster [Mn₄Sn₆S₂₀]⁸⁻: Solvothermal syntheses, crystal structures and photocatalytic properties of Mn(II) chalcogenidostannates|url=https://linkinghub.elsevier.com/retrieve/pii/S1387700318302454|journal=Inorganic Chemistry Communications|language=en|volume=93|pages=73–77|doi=10.1016/j.inoche.2018.05.004|s2cid=104109618 |url-access=subscription}}</ref> |- |{Mn(tepa)}₂(''μ''-Sn₂S₆) |tetragonal |''I''4₁/''a'' |a=25.977 c=10.041 Z=8 |6775 |1.800 |yellow |<ref name="MS"/> |- |{[Mn(trien)]₂[SnS₄]} | | | | | | |<ref name="CC"/> |- |{[Mn(C₆H₁₈N₄)]₂SnS₄}'''·'''4H₂O |monoclinic |''P''2₁/''c'' |''a'' 10.8446 ''b'' 20.974 ''c'' 13.2746 ''β'' 113.487° | | | |<ref>{{Cite journal|last1=Pienack|first1=Nicole|last2=Näther|first2=Christian|last3=Bensch|first3=Wolfgang|date=April 2009|title=The Inorganic-Organic Hybrid Compound {[Mn(trien)]₂SnS₄}·4H₂O: Exhibiting a Hitherto Unknown Binding Mode of the [SnS₄]^4- Tetrahedron|url=https://onlinelibrary.wiley.com/doi/10.1002/ejic.200801093|journal=European Journal of Inorganic Chemistry|language=en|volume=2009|issue=12|pages=1575–1577|doi=10.1002/ejic.200801093|url-access=subscription}}</ref> |- |{[Mn(phen)₂]₂(μ₂-Sn₂S₆)} |monoclinic |''P''2₁/''n'' |''a'' =10.8230 ''b''=9.8940 ''c''=24.811 ''β''=91.356° | | | |<ref name=":25">{{Cite journal|last1=Hilbert|first1=Jessica|last2=Näther|first2=Christian|last3=Bensch|first3=Wolfgang|date=2014-06-02|title=Influence of the Synthesis Parameters onto Nucleation and Crystallization of Five New Tin–Sulfur Containing Compounds|url=https://pubs.acs.org/doi/10.1021/ic500369m|journal=Inorganic Chemistry|language=en|volume=53|issue=11|pages=5619–5630|doi=10.1021/ic500369m|pmid=24845345|issn=0020-1669|url-access=subscription}}</ref> |- |{[Mn(phen)₂]₂(μ₂-Sn₂S₆)}·phen |triclinic |''P''{{overbar|1}} |''a''=10.0642 ''b''=10.6249 ''c''=13.693, ''α''=71.700° ''β''=81.458° ''γ''=84.346° | | | |<ref name=":25"/> |- |{[Mn(phen)₂]₂[Sn₂S₆]}'''·'''phen'''·'''H₂O phen = 1,10-phenanthroline |triclinic |''P''{{overbar|1}} |''a''=11.3203 ''b''=12.1436 ''c''=12.7586, ''α''=113.200° ''β''=90.908° ''γ''=110.974° | | | |<ref name="CC"/><ref name=":25"/> |- |[Mn(phen)]₂(SnS₄)·H₂O |monoclinic |''C''2/''m'' |a=16.146 b=19.262 c=9.938 ''β''=124.970 Z=4 |2532.6 |1.928 |red chain |<ref>{{Cite journal|last1=Liu|first1=Guang-Ning|last2=Guo|first2=Guo-Cong|last3=Chen|first3=Feng|last4=Guo|first4=Sheng-Ping|last5=Jiang|first5=Xiao-Ming|last6=Yang|first6=Chen|last7=Wang|first7=Ming-Sheng|last8=Wu|first8=Mei-Feng|last9=Huang|first9=Jin-Shun|date=2010|title=Stabilization of (SnS₄)⁴⁻ anion by coordinating to [TM(π-conjugated-ligand)m]n+ complex: a chain-like thiostannate(iv) {[Mn(phen)]₂(SnS₄)}n·nH₂O exhibiting an unprecedented link mode of the (SnS₄)⁴⁻ anion|url=http://xlink.rsc.org/?DOI=c0ce00292e|journal=CrystEngComm|language=en|volume=12|issue=12|page=4035|doi=10.1039/c0ce00292e|issn=1466-8033|url-access=subscription}}</ref> |- |{[Mn(phen)₂]₂[μ-η²-η²-SnS₄]₂[Mn(phen)]₂}·H₂O |triclinic |''P''{{overbar|1}} |''a''=10.8703 ''b''=12.5183 ''c''=14.9644, ''α''=103.381° ''β''=108.390° ''γ''=101.636° | | | |<ref name=":25"/> |- |{[Mn(2,2′-bipy)₂]₂[Sn₂S₆]} | | | | | | |<ref name=":18">{{Cite journal|last1=Hilbert|first1=Jessica|last2=Pienack|first2=Nicole|last3=Lühmann|first3=Henning|last4=Näther|first4=Christian|last5=Bensch|first5=Wolfgang|date=December 2016|title=Transition Metal Complexes with Linkage to the Thiostannate Units Forced by Suitable Amine Molecules: Transition Metal Complexes with Linkage to the Thiostannate Units Forced by Suitable Amine Molecules|url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.201600318|journal=Zeitschrift für anorganische und allgemeine Chemie|language=en|volume=642|issue=24|pages=1427–1434|doi=10.1002/zaac.201600318|url-access=subscription}}</ref> |- |(1,4-dabH)₂MnSnS₄ 1,4-dab = 1,4-diaminobutane |orthorhombic |''Fdd''2 |''a'' = 22.812, ''b'' = 24.789, ''c'' = 6.4153, ''Z'' = 8 |3627.8 | | |<ref>{{Cite journal|last1=Pienack|first1=Nicole|last2=Möller|first2=Karina|last3=Näther|first3=Christian|last4=Bensch|first4=Wolfgang|date=December 2007|title=(1,4-dabH)₂MnSnS₄: The first thiostannate with integrated Mn²⁺ ions in an anionic chain structure|url=https://linkinghub.elsevier.com/retrieve/pii/S1293255807002075|journal=Solid State Sciences|language=en|volume=9|issue=12|pages=1110–1114|doi=10.1016/j.solidstatesciences.2007.07.030|bibcode=2007SSSci...9.1110P|url-access=subscription}}</ref> |- |Li₄MnSn₂Se₇ |monoclinic |''Cc'' |a=18.126 b=7.2209 c=10.740 ''β''=93.43 Z=4 |1403.2 |4.132 |orange |<ref>{{cite journal |last1=Kaib |first1=Thomas |last2=Haddadpour |first2=Sima |last3=Andersen |first3=Hanne Flåten |last4=Mayrhofer |first4=Leonhard |last5=Järvi |first5=Tommi T. |last6=Moseler |first6=Michael |last7=Möller |first7=Kai-Christian |last8=Dehnen |first8=Stefanie |title=Quaternary Diamond-Like Chalcogenidometalate Networks as Efficient Anode Material in Lithium-Ion Batteries |journal=Advanced Functional Materials |date=10 December 2013 |volume=23 |issue=46 |pages=5693–5699 |doi=10.1002/adfm.201301025|s2cid=93236286}}</ref> |- |Fe₂SnS₄ |tetragonal |''I''4₁/''a'' |a=7.308 c=10.338 Z=4 |552 |4.32 | |<ref name="ES"/> |- |{[Fe(tepa)]₂[Sn₂S₆]} |tetragonal |''I''4₁/''a'' | | | | |<ref name="CC"/><ref name=":29">{{Cite journal|last1=Pienack|first1=Nicole|last2=Lehmann|first2=Stefanie|last3=Lühmann|first3=Henning|last4=El-Madani|first4=Marzog|last5=Näther|first5=Christian|last6=Bensch|first6=Wolfgang|date=October 2008|title=Solvothermal Syntheses, Crystal Structures and Selected Optical Properties of [ M(C₈N₅H₂₃)]₂Sn₂S₆ ( M = Co, Fe, Ni; C₈N₅H₂₃ = tetraethylenepentamine)|url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.200800282|journal=Zeitschrift für anorganische und allgemeine Chemie|language=en|volume=634|issue=12–13|pages=2323–2329|doi=10.1002/zaac.200800282|url-access=subscription}}</ref> |- |{[Fe(1,2-dach)₂][Sn₂S₆]}'''·'''2(1,2-dachH) | | | | | | |<ref name="CC"/> |- |{[Fe(phen)₂]₂[Sn₂S₆]}'''·'''phen'''·'''H₂O | | | | | | |<ref name="CC"/> |- |[Co(en)₃]₂[Sn₂S₆] |orthorhombic |''Pbca'' |a=15.640 b=11.564 c=18.742 Z=4 |2289.7 |1.779 |yellow |<ref name="CC"/><ref name=":14"/> |- |[Co(dien)₂]₂[Sn₂S₆] | | | | | | |<ref name="CC"/> |- |[Co₂(cyclam)₂Sn₂S₆]·2H₂O | | | | | | |<ref>{{Cite journal|last1=Zeisler|first1=Christoph|last2=Näther|first2=Christian|last3=Bensch|first3=Wolfgang|date=2013|title=A new synthetic approach to force bond formation between a transition metal complex and a thiostannate anion: solvothermal synthesis and crystal structure of [Co₂(cyclam)₂Sn₂S₆]·2H₂O|url=http://xlink.rsc.org/?DOI=c3ce40976g|journal=CrystEngComm|language=en|volume=15|issue=44|page=8874|doi=10.1039/c3ce40976g|bibcode=2013CEG....15.8874Z |issn=1466-8033|url-access=subscription}}</ref> |- |[Co(tren)]₂Sn₂S₆ |monoclinic |''C''2/''c'' |a=12.228 b=9.7528 c=23.285 ''β''=102.90 |2706.8 | | |<ref name="CC"/><ref name="DV"/> |- |{[Co(cyclam)]₂[Sn₂S₆]}''_n'''''·'''2''n''H₂O cyclam = 1,4,8,11-tetraazacyclotetradecane | | | | | | |<ref name="CC"/> |- |{[Co(tepa)]₂[Sn₂S₆]} tepa=tetraethylenepentamine |tetragonal |''I''4₁/''a'' |a=25.742 c=9.898 |6558 | | |<ref name="CC"/><ref name=":29"/><ref name="DV"/> |- |{[Co(phen)₂]₂[Sn₂S₆]}'''·'''phen'''·'''H₂O | | | | | | |<ref name="CC"/> |- |[Co(2-(aminomethyl)pyridine)₃]₂Sn₂S₆'''·'''10H₂O (2amp) |monoclinic |''P''2₁/''c'' |a=10.1443 b=14.6124 c=18.8842 ''β''=90.601° Z=2 |2799.1 |1.633 |yellow |<ref name=":10">{{Cite journal|last1=Lühmann|first1=Henning|last2=Jeß|first2=Inke|last3=Näther|first3=Christian|last4=Bensch|first4=Wolfgang|date=2020-02-28|title=Crystal Structures and Selected Properties of Co II Containing Thiostannates prepared by a New Room Temperature Route|journal=Zeitschrift für anorganische und allgemeine Chemie|language=en|volume=646|issue=4|pages=234–240|doi=10.1002/zaac.201900227|issn=0044-2313|doi-access=free}}</ref> |- |[Co(''trans''-1,2-diaminocyclohexane)₃]₂Sn₂S₆'''·'''8H₂O (dach) |monoclinic |''P''2₁/''n'' |a=12.6521 b=11.7187 c=20.4386 ''β''=91.262° Z=2 |3029.6 |1.509 |red |<ref name=":10"/> |- |Ni₆SnS₂ Butianite |tetragonal |''I''4/''mmm'' |a = 3.650, c = 18.141 Z=2 |241.7 |7.62 |opaque |<ref>{{Cite web|title=Butianite|url=https://www.mindat.org/min-47863.html|access-date=2021-07-08|website=www.mindat.org}}</ref> |- |[Ni(en)₃]₂[Sn₂S₆] | | | | | | |<ref name="CC"/> |- |[Ni(dap)₃]₂[Sn₂S₆]'''·'''2H₂O dap=1,2-diaminopropane |triclinic |''P''{{overbar|1}} |a=9.9046 b=10.527 c=11.319 ''α'' =72.13° ''β'' =85.19° ''γ'' =63.63° |1004.5 | | |<ref name="CC"/><ref name="DV"/> |- |[Ni(1,2-dach)₃]₂[Sn₂S₆]'''·'''4H₂O 1,2-dach = 1,2-diaminocyclohexane | | | | | | |<ref name="CC"/> |- |[Ni(dien)₂]₂[Sn₂S₆] | | | | | | |<ref name="CC"/> |- |{[Ni(cyclen)]₆[Sn₆S₁₂O₂(OH)₆]}'''·'''2(ClO₄)'''·'''19H₂O cyclen = 1,4,7,10-tetraazacyclododecane | | | | | | |<ref name=":6">{{Cite thesis|last=Benkada|first=Assma|date=2020-11-30|title=Synthesis of Thiostannates, Oxo-Thiostannates and Tin-Sulfides Applying Transition Metal Complexes Containing Macrocyclic Amine Molecules: Development of new synthetic routes to synthesize Sn-S and S-Sn-O compounds and investigation of their properties|url=https://macau.uni-kiel.de/receive/macau_mods_00000864|language=en}}</ref> |- |[Ni(cyclen)(H₂O)₂]₄[Sn₁₀S₂₀O₄]'''·~'''13H₂O | | | | | | |<ref name=":6"/> |- |{[Ni(cyclen)]₆[Sn₆S₁₂O₂(OH)₆]}'''·'''2(ClO₄)'''·'''19H₂O |monoclinic |''C''2/''c'' |a=25.7223 b=15.6522 c=29.070 ''β''=105.879 Z=4 |11257 |1.863 |oxothiostannate |<ref>{{Cite journal|last1=Benkada|first1=Assma|last2=Poschmann|first2=Michael|last3=Näther|first3=Christian|last4=Bensch|first4=Wolfgang|date=2019-02-28|title=New Transition Metal Oxo-Thiostannate: Synthesis, Characterization, and Investigation of its Photocatalytic Properties: New Transition Metal Oxo-Thiostannate: Synthesis, Characterization, and Investigation of its Photocatalytic Properties|url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.201800475|journal=Zeitschrift für anorganische und allgemeine Chemie|language=en|volume=645|issue=4|pages=433–439|doi=10.1002/zaac.201800475|s2cid=104376198 |url-access=subscription}}</ref> |- |[Ni(2amp)₃]₂[Sn₂S₆]'''·'''9.5H₂O 2amp = 2-(aminomethyl)pyridine |monoclinic |''P''2₁/''n'' |a=18.7021 b=14.6141 c=20.2591 ''β=''97.696 Z=4 |5487.2 |1.655 |purple |<ref name="FR"/> |- |[Ni(aepa)₂]₂[Sn₂S₆] aepa=''N''-2-aminoethyl-1,3-propandiamine | | | | | | |<ref name="CC"/> |- |[Ni(tren)]₂Sn₂S₆ |monoclinic |''C''2/''c'' |a=23.371 b=8.231 c=14.274 ''β'' =107.230 Z=4 |2622.6 |2.127 | |<ref name="CC"/><ref name=":19">{{Cite journal|last1=Hilbert|first1=Jessica|last2=Näther|first2=Christian|last3=Weihrich|first3=Richard|last4=Bensch|first4=Wolfgang|date=2016-08-15|title=Room-Temperature Synthesis of Thiostannates from {[Ni(tren)]₂[Sn₂S₆]}_n|url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.6b00625|journal=Inorganic Chemistry|language=en|volume=55|issue=16|pages=7859–7865|doi=10.1021/acs.inorgchem.6b00625|pmid=27479453|issn=0020-1669|url-access=subscription}}</ref> |- |[Ni(tren)₂]₂[Sn₂S₆]'''·'''8H₂O |orthorhombic |''P''4₂/''n'' |''a''=26.1885 ''b''=26.1885 ''c''=11.1122 | | | |<ref name="CC"/><ref name=":17">{{Cite journal|last1=Hilbert|first1=Jessica|last2=Näther|first2=Christian|last3=Bensch|first3=Wolfgang|date=April 2017|title=Studies of the reactivity of {[Ni(tren)]₂[Sn₂S₆]}: Synthesis and crystal structures of two new thiostannates prepared at room temperature|url=https://linkinghub.elsevier.com/retrieve/pii/S0020169316308039|journal=Inorganica Chimica Acta|language=en|volume=459|pages=29–35|doi=10.1016/j.ica.2017.01.018|url-access=subscription}}</ref> |- |[Ni(tren)(2amp)]₂[Sn₂S₆] |triclinic |''P''{{overbar|1}} |''a'' =10.2878 ''b'' =11.1100 ''c'' =11.4206, ''α'' =84.740° ''β'' =84.395° ''γ'' =79.093° | | | |<ref name="CC"/><ref name=":17"/> |- |[Ni(tren)(2amp)]₂[Sn₂S₆]·10H₂O |monoclinic |''P''2₁/''n'' |''a'' =12.1933 ''b'' =13.4025 ''c'' =14.8920 ''β''= 103.090° | | | |<ref name=":20">{{Cite journal|last1=Hilbert|first1=Jessica|last2=Näther|first2=Christian|last3=Bensch|first3=Wolfgang|date=2017-09-06|title=Applying Ni(II) Amine Complexes and Sodium Thiostannate as Educts for the Generation of Thiostannates at Room Temperature|url=https://pubs.acs.org/doi/10.1021/acs.cgd.7b00728|journal=Crystal Growth & Design|language=en|volume=17|issue=9|pages=4766–4775|doi=10.1021/acs.cgd.7b00728|bibcode=2017CrGrD..17.4766H |issn=1528-7483|url-access=subscription}}</ref> |- |[Ni(tren)(en)]₂[Sn₂S₆]·2H₂O |monoclinic |''P''2₁/''n'' |''a'' 12.7041 ''b'' 9.8000 ''c'' 15.3989, ''β'' 108.843° | | | |<ref name=":20"/> |- |[Ni(tren)(en)]₂[Sn₂S₆]·6H₂O |monoclinic |''P''2₁/''n'' |''a'' 12.5580 ''b'' 9.7089 ''c'' 16.0359, ''β'' 91.827° | | | |<ref name=":20"/> |- |[Ni(tren)(1,2-dach)]₂[Sn₂S₆]·3H₂O |triclinic |''P''{{overbar|1}} |''a'' 9.8121 ''b'' 10.0080 ''c'' 12.422, ''α'' 86.38° ''β'' 79.65° ''γ'' 65.72° | | | |<ref name=":20"/> |- |[Ni(tren)(1,2-dach)]₂[Sn₂S₆]·4H₂O |monoclinic |''P''2₁/''n'' |''a'' 10.7119 ''b'' 19.0797 ''c'' 11.1005, ''β'' 104.803° | | | |<ref name=":20"/> |- |{[Ni(cyclam)]₂[Sn₂S₆]}'''·'''2H₂O | | | | | | |<ref name="CC"/> |- |{[Ni(tepa)]₂[Sn₂S₆]} |monoclinic |''P''2₁/''n'' | | | | |<ref name="CC"/><ref name=":29"/> |- |{[Ni(phen)₂]₂[Sn₂S₆]}'''·'''2,2′-bipy |monoclinic |''P''2₁/''n'' |a=10.5715 b=9.9086 c=24.9960 ''β''=92.800 Z=2 |2615.17 |1.809 |deep red |<ref name="CC"/><ref name=":23">{{Cite journal|last1=Hilbert|first1=J.|last2=Näther|first2=C.|last3=Bensch|first3=W.|date=2015|title=Utilization of mixtures of aromatic N-donor ligands of different coordination ability for the solvothermal synthesis of thiostannate containing molecules|journal=Dalton Transactions|language=en|volume=44|issue=25|pages=11542–11550|doi=10.1039/C5DT01145K|pmid=26031892|issn=1477-9226|doi-access=free}}</ref> |- |{[Ni(phen)₂]₂Sn₂S₆}·4,4′-bipy·½H₂O 4,4′-bipy = 4,4′-bipyridine |monoclinic |''C''2/''c'' |a=18.3431 b=19.4475 c=15.0835 ''β''=95.556 Z=4 |5355.4 |1.789 |dark red-brown |<ref name=":23"/> |- |{[Ni(phen)₂]₂[Sn₂S₆]}'''·'''phen'''·'''H₂O | | | | | | |<ref name=":18"/> |- |[Ni(L₁)][Ni(L₁)Sn₂S₆]''_n'''''·'''2H₂O L₁ = 1,8-dimethyl-1,3,6,8,10,13-hexaazacyclotetradecane |monoclinic |''P''21/''c'' | | | | |<ref name=":16">{{Cite journal|last1=Benkada|first1=Assma|last2=Näther|first2=Christian|last3=Bensch|first3=Wolfgang|date=2020-08-31|title=Room Temperature Synthesis of New Thiostannates by Slow Interdiffusion of Different Solvents|journal=Zeitschrift für anorganische und allgemeine Chemie|language=en|volume=646|issue=16|pages=1352–1358|doi=10.1002/zaac.202000199|issn=0044-2313|doi-access=free}}</ref> |- |[Ni(L₂)]₂[Sn₂S₆]'''·'''4H₂O L₂ = 1,8-diethyl-1,3,6,8,10,13-hexaazacyclotetradecane |triclinic |''P''{{overbar|1}} | | | | |<ref name=":16"/> |- |[Ni(tren)(ma)(H₂O)]₂[Sn₂S₆]·4H₂O ma = methylamine |monoclinic |''P''2₁/''n'' |a=11.1715 b=10.5384 c=15.8594 Z=2 |1827.45 |1.835 | |<ref name=":19"/> |- |[Ni(tren)(1,2-dap)]₂[Sn₂S₆]·2H₂O |monoclinic |''P''2₁/''n'' |a=12.9264 b=10.1627 c=15.6585 Z=2 |1889.8 |1.799 | |<ref name=":19"/> |- |[Ni(tren)(1,2-dap)]₂[Sn₂S₆]·4H₂O |monoclinic |''C''2/''c'' |''a'' =14.3925 ''b''=15.1550 ''c''=18.9307, ''β''=99.108° | | | |<ref name=":20"/> |- |[Ni(2amp)₃]₂[Sn₂S₆]'''·'''9.5H₂O 2amp = 2-(aminomethyl)pyridine |monoclinic |''P''2₁/''n'' |a=18.7021 b=14.6141 c=20.2591 Z=4 |5487.23 |1.655 |purple |<ref name="FR"/> |- |Cu₂SnS₃ Mohite |monoclinic | |a=23.10 b=6.25 c=6.25 ''β''=101.0° | |4.69 |greenish grey |<ref name="ES"/><ref>{{Cite web|title=Mohite|url=https://www.mindat.org/min-2741.html|access-date=2021-07-15|website=www.mindat.org}}</ref> |- |Cu₃SnS₄ Kuramite |tetragonal |''I''{{overbar|4}}2''m'' |a = 5.445, c = 10.75, Z = 2 |318.72 |4.56 | |<ref>{{Cite web|title=Kuramite Mineral Data|url=http://webmineral.com/data/Kuramite.shtml|access-date=2021-07-08|website=webmineral.com}}</ref> |- |Cu₄SnS₄ |orthorhombic |''Pnma'' |a=13.70 b=7.750 c=6.454 Z=4 |685 |4.96 | |<ref name="ES"/> |- |Cu₄SnS₆ Erazoite |rhombohedral |''R''3''m'' |''a'' = 3.739, ''c'' = 32.941, Z = 2 | |4.53 |black |<ref>{{Cite journal|last1=Chen|first1=X.-a|last2=Wada|first2=H|last3=Sato|first3=A|date=January 1999|title=Preparation, crystal structure and electrical properties of Cu₄SnS₆|url=https://linkinghub.elsevier.com/retrieve/pii/S0025540899000136|journal=Materials Research Bulletin|language=en|volume=34|issue=2|pages=239–247|doi=10.1016/S0025-5408(99)00013-6|url-access=subscription}}</ref> |- |Cu₄Sn₇S₁₆ |monoclinic | |a=12.75 b=7.34 c=12.71 ''β''=109.5 Z=2 |1121 |4.74 | |<ref name="ES"/> |- |(DBUH)CuSnS₃ DBU = 1,8-diazabicyclo[5.4.0]undec-7-ene |monoclinic |''P''2₁/''n'' |''a''=9.254 ''b''=8.6190 ''c''=18.135, ''β''=92.80° | | | |<ref>{{Cite journal|last1=Pienack|first1=Nicole|last2=Näther|first2=Christian|last3=Bensch|first3=Wolfgang|date=January 2007|title=Two new copper thiostannates synthesised under solvothermal conditions: Crystal structures, spectroscopic and thermal properties of (DBUH)CuSnS₃ and (1,4-dabH₂)Cu₂SnS₄|url=https://linkinghub.elsevier.com/retrieve/pii/S1293255806002767|journal=Solid State Sciences|language=en|volume=9|issue=1|pages=100–107|doi=10.1016/j.solidstatesciences.2006.11.012|bibcode=2007SSSci...9..100P|url-access=subscription}}</ref> |- |(1,4-dabH₂)Cu₂SnS₄ 1,4-dab = 1,4-diaminobutane |tetragonal |''P''4₂/''n'' |''a''=14.539 ''c''=11.478 | | | |<ref name="SA"/> |- |(''en''H)₆Cu₄₀Sn₁₅S₆₀ en=ethylenediamine |cubic |''Pn''{{overbar|3}}''n'' |a=25.260 Z=4 |16119 |2.727 |black |<ref name="TD">{{Cite journal|last1=Behrens|first1=Malte|last2=Ordolff|first2=Marie-Eve|last3=Näther|first3=Christian|last4=Bensch|first4=Wolfgang|last5=Becker|first5=Klaus-Dieter|last6=Guillot-Deudon|first6=Catherine|last7=Lafond|first7=Alain|last8=Cody|first8=Jason A.|date=2010-09-20|title=New Three-Dimensional Thiostannates Composed of Linked Cu₈S₁₂ Clusters and the First Example of a Mixed-Metal Cu₇SnS₁₂ Cluster|url=https://pubs.acs.org/doi/10.1021/ic100688z|journal=Inorganic Chemistry|language=en|volume=49|issue=18|pages=8305–8309|doi=10.1021/ic100688z|pmid=20726515|issn=0020-1669|url-access=subscription}}</ref> |- |(''en''H)₃Cu₇Sn₄S₁₂ |trigonal |''R''{{overbar|3}}''c'' |a=13.532 c=28.933 Z=6 |4588 |3.23 |red |<ref name="TD"/> |- |[H₂en]₂[Cu₈Sn₃S₁₂] | | | | | | |<ref name="CC"/> |- |(''tren''H_''3'')Cu₇Sn₄S₁₂ ''tren'' = tris(2-aminoethyl)amine) |trigonal |''R''3''c'' |a=13.1059 c=29.347 Z=6 |4365.4 |3.317 | |<ref name="TD"/> |- |[dienH₂][Cu₂Sn₂S₆] | | | | | | |<ref name="CC"/> |- |[DBUH][CuSnS₃] DBU = 1,8-diazabicyclo[5.4.0]undec-7-ene | | | | | | |<ref name="CC"/> |- |[1,4-dabH₂][Cu₂SnS₄] | | | | | | |<ref name="CC"/> |- |{[Cu(cyclam)]₂[Sn₂S₆]}'''·'''2H₂O cyclam=1,4,8,11-tetraazacyclotetradecane |triclinic |''P''{{overbar|1}} |''a''=9.0580 ''b''=9.9419 ''c''=10.2352, ''α''=97.068° ''β''=94.314° ''γ''=101.514° | | | |<ref name="CC"/> |- |(DBNH)₂Cu₆Sn₂S₈ DBN=1,5-diazabicyclo[4.3.0]non-7-ene | | | | | | |<ref name=":28"/> |- |[Co(2-(aminomethyl)pyridine)₃]₂ Sn₂S₆'''·'''10H₂O |monoclinic |''P''2₁/''c'' |''a''=10.1443 ''b''=14.6124 ''c''=18.8842 ''β''=90.601° Z=2 |2799.1 |1.633 |yellow; unstable |<ref name=":49">{{Cite journal |last1=Lühmann |first1=Henning |last2=Jeß |first2=Inke |last3=Näther |first3=Christian |last4=Bensch |first4=Wolfgang |date=2020-02-28 |title=Crystal Structures and Selected Properties of Co II Containing Thiostannates prepared by a New Room Temperature Route |journal=Zeitschrift für anorganische und allgemeine Chemie |language=en |volume=646 |issue=4 |pages=234–240 |doi=10.1002/zaac.201900227 |s2cid=214133328 |issn=0044-2313|doi-access=free}}</ref> |- |[Co(''trans''-1,2-diaminocyclohexane)₃]₂Sn₂S₆'''·'''8H₂O |monoclinic |''P''2₁/''n'' |''a''=12.6521 ''b''=11.7187 ''c''=20.4386 ''β''=91.262° Z=2 |3029.6 |1.509 |red |<ref name=":49"/> |- |Na₄Cu₃₂Sn₁₂S₄₈·4H₂O |cubic |''Fm''{{overbar|3}}''c'' |''a'' = 17.921 ''z'' = 13 | | |black; absorption edge 2.0 eV |<ref name="SS"/> |- |CuAlSnS₄ |cubic | |a=10.28 Z=8 |1074 |4.17 | |<ref name="ES"/> |- |K₁₁Cu₃₂Sn₁₂S₄₈·4H₂O |cubic |''Fm''{{overbar|3}}''c'' |''a'' = 18.0559 ''z'' = 14.75 | | |black; absorption edge 1.9 eV |<ref name="SS">{{Cite journal|last1=Zhang|first1=Xian|last2=Wang|first2=Qiuran|last3=Ma|first3=Zhimin|last4=He|first4=Jianqiao|last5=Wang|first5=Zhe|last6=Zheng|first6=Chong|last7=Lin|first7=Jianhua|last8=Huang|first8=Fuqiang|date=2015-06-01|title=Synthesis, Structure, Multiband Optical, and Electrical Conductive Properties of a 3D Open Cubic Framework Based on [Cu₈Sn₆S₂₄]_z − Clusters|url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.5b00317|journal=Inorganic Chemistry|language=en|volume=54|issue=11|pages=5301–5308|doi=10.1021/acs.inorgchem.5b00317|pmid=25955506 |issn=0020-1669|url-access=subscription}}</ref> |- |Cu₂MnSnS₄ |tetragonal | |a=5.49 c=10.72 Z=2 |323 |4.41 | |<ref name="ES"/> |- |Cu₂FeSnS₄ Stannite Ferrokësterite |tetragonal |''I''{{overbar|4}}2''m'' |a = 5.4432, c = 10.7299 Z=2 |317.91 | |grey |<ref>{{Cite web|title=Stannite|url=https://www.mindat.org/min-3747.html|access-date=2021-07-08|website=www.mindat.org}}</ref> |- |Cu₂FeSn₃S₈ |tetragonal |I4₁/a |a=7.29 c=10.31 Z=2 |548 |4.82 | |<ref name="ES"/> |- |Cu₆Fe₂SnS₈ Mawsonite |Tetragonal |''P''{{overbar|4}}''m''2 |a = 7.603, c = 5.358 Z=1 |309 |4.65 |brownish orange |<ref>{{Cite web|title=Mawsonite|url=https://www.mindat.org/min-2604.html|access-date=2021-07-15|website=www.mindat.org}}</ref> |- |Cu₆FeSn₂S₈ Chatkalite |Tetragonal |''P{{overbar|4}}m''2 |a = 7.61, c = 5.373 Z=1 |311.1 |5.00 | |<ref>{{Cite web|title=Chatkalite|url=https://www.mindat.org/min-973.html|access-date=2021-07-08|website=www.mindat.org}}</ref> |- |Cu₂CoSnS₄ |Tetragonal |''I''{{overbar|4}}2''m'' |a=5.402 c=10.805 Z=2 |315 |4.56 | |<ref name="ES"/> |- |Cu₂NiSnS₄ | | |a=5.425 Z=1 |160 |4.49 | |<ref name="ES"/> |- |Cu₁₃VSn₃S₁₆ Nekrasovite |isometric | |a=10.73 |1,235 | |brown |<ref>{{Cite web|title=Nekrasovite|url=https://www.mindat.org/min-2873.html|access-date=2021-07-15|website=www.mindat.org}}</ref> |- |[Zn(en)₃]₂[Sn₂S₆] |orthorhombic |''Pbca'' |a=15.452 b=11.524 c=18.614 Z=4 |3315.3 |1.845 |colourless |<ref name="CC"/><ref name=":14"/> |- |{Zn(tren)}₂(''μ''-Sn₂S₆) |monoclinic |''C''2/''c'' |''a'' 12.214 ''b'' 9.726 ''c'' 23.209 ''β'' 102.732° |2689.3 |2.107 |light yellow |<ref name="MS"/><ref>{{Cite web|title=Search Results – Access Structures|url=https://www.ccdc.cam.ac.uk/structures/search?pid=ccdc:1008493|access-date=2021-07-14|website=www.ccdc.cam.ac.uk}}</ref> |- |Cu₂ZnSnS₄ Kësterite |tetragonal |''I''{{overbar|4}} |a = 5.427, c = 10.871 Z=2 |320.18 |4.55 |greenish black |<ref>{{Cite web|title=Kësterite|url=https://www.mindat.org/min-2189.html|access-date=2021-07-08|website=www.mindat.org}}</ref> |- |Cu₆⁺Cu₂²⁺(Fe²⁺,Zn)₃Sn₂S₁₂ Stannoidite |orthorhombic | |a = 10.76, b = 5.4, c = 16.09 |934.9 |4.68 |brass |<ref>{{Cite web|title=Stannoidite|url=https://www.mindat.org/min-3748.html|access-date=2021-07-15|website=www.mindat.org}}</ref> |- |Cu₃(V,Ge,Sn)S₄ Ge-Sn-Sulvanite | | | |361 | | |<ref>{{Cite web|title=Ge-Sn-Sulvanite|url=https://www.mindat.org/min-40590.html|access-date=2021-07-15|website=www.mindat.org}}</ref> |- |SnGeS₃ Stangersite |monoclinic |''P''2₁/''b'' |a = 7.270, b = 10.197, c = 6.846 β = 105.34° Z=4 |489 |3.98 |orange | |- |Rb₄SnS₄ | | | | | | |<ref name="shel"/> |- |Rb₄Sn₂S₆ | | | | | | |<ref name="shel"/> |- |Rb₂Sn₃S₇'''·'''2H₂O | | | | | | |<ref name="shel"/> |- |Rb₂Cu₂SnS₄ |orthorhombic |Ibam |a=5.528 b=11.418 c=13.700 Z=4 |865 |4.185 |band gap 2.08 eV |<ref name=":13">{{Cite journal|last1=Liao|first1=Ju Hsiou|last2=Kanatzidis|first2=Mercouri G.|date=1993-10-01|title=Quaternary rubidium copper tin sulfides (Rb₂Cu₂SnS₄, A₂Cu₂Sn₂S₆ (A = Na, K, Rb, Cs), A₂Cu₂Sn₂Se₆ (A = K, Rb), potassium gold tin sulfides, K₂Au₂SnS₄, and K₂Au₂Sn₂S₆. Syntheses, structures, and properties of new solid-state chalcogenides based on tetrahedral [SnS₄]^4- units|url=https://pubs.acs.org/doi/abs/10.1021/cm00034a029|journal=Chemistry of Materials|language=en|volume=5|issue=10|pages=1561–1569|doi=10.1021/cm00034a029|issn=0897-4756|url-access=subscription}}</ref> |- |Rb₂Cu₂Sn₂S₆ |monoclinic |''C''2/''c'' |a=11.026 b=11.019 c=20.299 ''β''=97.79 Z=8 |2444 |3.956 |band gap 1.44 eV |<ref name=":13"/> |- |Rb₂ZnSn₃S₈ | | | | | | |<ref name="tian">{{cite journal |last1=Tian |first1=Tian |last2=Li |first2=Zefen |last3=Wang |first3=Naizheng |last4=Zhao |first4=Sangen |last5=Xu |first5=Jiayue |last6=Lin |first6=Zheshuai |last7=Mei |first7=Dajiang |title=Cs ₂ ZnSn ₃ S ₈: A Sulfide Compound Realizes a Large Birefringence by Modulating the Dimensional Structure |journal=Inorganic Chemistry |date=2021-06-16 |volume=60 |issue=13 |pages=9248–9253 |doi=10.1021/acs.inorgchem.1c01024|pmid=34132527 |s2cid=235450479}}</ref> |- |[Rb₄(H₂O)₄][SnS₄] | | | | | | |<ref name="NH"/> |- |Sr₃MnSn₂S₈ |cubic |''I''{{overbar|4}}3''d'' |''a'' = 14.2287 ''Z'' = 8 |2880.7 |3.743 |dark green |<ref>{{Cite journal|last1=Liu|first1=Chuang|last2=Mei|first2=Dajiang|last3=Cao|first3=Wangzhu|last4=Yang|first4=Yi|last5=Wu|first5=Yuandong|last6=Li|first6=Guobao|last7=Lin|first7=Zheshuai|date=2019|title=Mn-Based tin sulfide Sr₃MnSn₂S₈ with a wide band gap and strong nonlinear optical response|url=http://xlink.rsc.org/?DOI=C8TC05904G|journal=Journal of Materials Chemistry C|language=en|volume=7|issue=5|pages=1146–1150|doi=10.1039/C8TC05904G|s2cid=139249564 |issn=2050-7526|url-access=subscription}}</ref> |- |Cu₂SrSnS₄ |trigonal |''P''3₁ |a = 6.29, c = 15.57 Z=3 |534 |4.31 | |<ref>{{Cite journal|last=Teske|first=Chr. L.|date=January 1976|title=Darstellung und Kristallstruktur von Cu₂SrSnS₄|url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.19764190112|journal=Zeitschrift für anorganische und allgemeine Chemie|language=de|volume=419|issue=1|pages=67–76|doi=10.1002/zaac.19764190112|issn=0044-2313|url-access=subscription}}</ref><ref name="ES"/> |- |Sr₆Cu₄Sn₄S₁₆ |cubic |''I''{{overbar|4}}3''d'' |a=13.982 |2734 |4.295 |yellow |<ref name="PP">{{Cite journal|last1=Yang|first1=Ya|last2=Song|first2=Miao|last3=Zhang|first3=Jie|last4=Gao|first4=Lihua|last5=Wu|first5=Xiaowen|last6=Wu|first6=Kui|date=2020|title=Coordinated regulation on critical physiochemical performances activated from mixed tetrahedral anionic ligands in new series of Sr₆A₄M₄S₁₆ (A = Ag, Cu; M = Ge, Sn) nonlinear optical materials|url=http://xlink.rsc.org/?DOI=D0DT00432D|journal=Dalton Transactions|language=en|volume=49|issue=11|pages=3388–3392|doi=10.1039/D0DT00432D|pmid=32104856|s2cid=211535947 |issn=1477-9226|url-access=subscription}}</ref> |- |Sr₆Cu₂FeSn₄S₁₆ |cubic |''I''{{overbar|4}}3''d'' |a=14.1349 | | |band gap 1.53 eV |<ref name="OP">{{Cite journal|last1=Zhang|first1=Lingyun|last2=Mei|first2=Dajiang|last3=Wu|first3=Yuanwang|last4=Shen|first4=Chenfei|last5=Hu|first5=Wenxin|last6=Zhang|first6=Lujia|last7=Li|first7=Jinjin|last8=Wu|first8=Yuandong|last9=He|first9=Xiao|date=April 2019|title=Syntheses, structures, optical properties, and electronic structures of Ba₆Cu₂GSn₄S₁₆ (G = Fe, Ni) and Sr₆D₂FeSn₄S₁₆ (D = Cu, Ag)|url=https://linkinghub.elsevier.com/retrieve/pii/S0022459619300374|journal=Journal of Solid State Chemistry|language=en|volume=272|pages=69–77|doi=10.1016/j.jssc.2019.01.024|bibcode=2019JSSCh.272...69Z|s2cid=104331229 |url-access=subscription}}</ref> |- |SrSnS₃ |orthorhombic |''Pnma'' |a=8.264 b=3.867 c=14.116 Z=4 |451 |4.45 | |<ref name="ES"/> |- |[Y₂(dien)₄(μ-OH)₂]Sn₂S₆ |monoclinic |''P''2₁/''n'' |a=11.854 b=11.449 c=13.803 ''β''=97.978 Z=2 |1855 |1.888 |light yellow |<ref name=":27">{{Cite journal|last1=Zhou|first1=Jian|last2=Liu|first2=Xing|last3=An|first3=Litao|last4=Hu|first4=Feilong|last5=Yan|first5=Wenbin|last6=Zhang|first6=Yunyan|date=2012-02-20|title=Solvothermal Synthesis and Characterization of a Series of Lanthanide Thiostannates(IV): The First Examples of Inorganic–Organic Hybrid Cationic Lanthanide Thiostannates(IV)|url=https://pubs.acs.org/doi/10.1021/ic2023083|journal=Inorganic Chemistry|language=en|volume=51|issue=4|pages=2283–2290|doi=10.1021/ic2023083|pmid=22280530|issn=0020-1669|url-access=subscription}}</ref> |- |''α-''Ag₈SnS₆ |cubic | |a=21.43 |9842 | | |<ref name="ES"/> |- |''β-''Ag₈SnS₆ |cubic | |a=10.85 |1277 | | |<ref name="ES"/> |- |Ag₈SnS₆ Canfieldite |orthorhombic | |a = 15.298, b = 7.548, c = 10.699 Z=4 |1,235.4 |6.311 |metallic |<ref>{{Cite web|title=Canfieldite|url=https://www.mindat.org/min-882.html|access-date=2021-07-15|website=www.mindat.org}}</ref> |- |Na₃AgSnS₄ |monoclinic |''P''2₁/''c'' |''a'' 8.109 ''b'' 6.483 ''c'' 15.941, ''α'' 90° ''β'' 103.713 | | |double chain |<ref>{{Cite journal|last1=Yang|first1=Ya|last2=Wu|first2=Kui|last3=Zhang|first3=Bingbing|last4=Wu|first4=Xiaowen|last5=Lee|first5=Ming-Hsien|date=2020-02-17|title=One-Dimensional Double Chains in Sodium-Based Quaternary Chalcogenides Displaying Intriguing Red Emission and Large Optical Anisotropy|url=https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.9b03444|journal=Inorganic Chemistry|language=en|volume=59|issue=4|pages=2519–2526|doi=10.1021/acs.inorgchem.9b03444|pmid=31999111|s2cid=210947790 |issn=0020-1669|url-access=subscription}}</ref> |- |AgCrSnS₄ |cubic | |a=10.74 Z=8 |1239 |4.92 | |<ref name="ES"/> |- |Ag₂MnSnS₄ – Agmantinite |orthorhombic | |a = 6.632, b = 6.922, c = 8.156 Z=2 | |4.574 |orange |<ref>{{Cite web|title=Agmantinite|url=https://www.mindat.org/min-46534.html|access-date=2021-07-08|website=www.mindat.org}}</ref> |- |Ag₂ZnSnS₄ Pirquitasite |tetragonal |''I''{{overbar|4}} |a = 5.78, c = 10.82 |361 | |black |<ref>{{Cite web|title=Pirquitasite|url=https://www.mindat.org/min-3219.html|access-date=2021-07-08|website=www.mindat.org}}</ref> |- |Ag₂(Fe²⁺,Zn)SnS₄ Hocartite |tetragonal |''I''{{overbar|4}}2''m'' |a = 5.74, c = 10.96 Z=2 |361 |4.77 |brownish grey |<ref>{{Cite web|title=Hocartite|url=https://www.mindat.org/min-1911.html|access-date=2021-07-15|website=www.mindat.org}}</ref> |- |Ag¹⁺(Fe²⁺_0.5Sn⁴⁺_1.5)S₄ Toyohaite |tetragonal | | | | |grey |<ref>{{Cite web|title=Toyohaite|url=https://www.mindat.org/min-4004.html|access-date=2021-07-15|website=www.mindat.org}}</ref> |- |[enH][Cu₂AgSnS₄] |orthorhombic |''Pnma'' |a=19.7256 b=7.8544 c= 6.5083 Z=4 |1008.3 |3.577 |red |<ref>{{Cite journal|last1=Xiong|first1=Wei-Wei|last2=Miao|first2=Jianwei|last3=Li|first3=Pei-Zhou|last4=Zhao|first4=Yanli|last5=Liu|first5=Bin|last6=Zhang|first6=Qichun|date=2014|title=[enH][Cu₂AgSnS₄]: a quaternary layered sulfide based on Cu–Ag–Sn–S composition|url=http://xlink.rsc.org/?DOI=C4CE00740A|journal=CrystEngComm|language=en|volume=16|issue=27|pages=5989–5992|doi=10.1039/C4CE00740A|bibcode=2014CEG....16.5989X |issn=1466-8033|url-access=subscription}}</ref> |- |Ag₂SrSnS₄ |orthorhombic | |a=7.127 b=8.117 c=6.854 Z=2 |397 |5.02 | |<ref name="ES"/> |- |Sr₆Ag₄Sn₄S₁₆ |cubic |''I''{{overbar|4}}3''d'' |a=14.2219 Z=4 |2876.6 |4.491 |yellow |<ref name="PP"/> |- |Sr₆Ag₂FeSn₄S₁₆ |cubic |''I''{{overbar|4}}3''d'' |a=14.2766 | | |band gap 1.87 eV |<ref name="OP"/> |- |[1,4-dabH₂][Ag₂SnS₄] 1,4-dab = 1,4-diaminobutane |tetragonal |''P''4₂/''n'' |a = 14.7847, c = 11.9087, Z = 8 |2603.1 | | |<ref name="CC"/><ref>{{Cite journal|last1=Pienack|first1=Nicole|last2=Bensch|first2=Wolfgang|date=August 2006|title=The New Silver Thiostannate (1,4-dabH₂)Ag₂SnS₄: Solvothermal Synthesis, Crystal Structure and Spectroscopic Properties|url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.200600111|journal=Zeitschrift für anorganische und allgemeine Chemie|language=de|volume=632|issue=10–11|pages=1733–1736|doi=10.1002/zaac.200600111|issn=0044-2313|url-access=subscription}}</ref> |- |[H₂en][Ag₂SnS₄] | | | | | | |<ref name="CC"/> |- |[CH₃NH₃]₂Ag₄Sn^IV₂Sn^IIS₈ |orthorhombic |''Pnma'' |''a'' =19.378 ''b'' =7.390 ''c'' =13.683 Z=4 |1959 |3.756 |Orange Sn(II) |<ref>{{Cite journal|last1=Zhang|first1=Bo|last2=Li|first2=Jun|last3=Du|first3=Cheng-Feng|last4=Feng|first4=Mei-Ling|last5=Huang|first5=Xiao-Ying|date=2016-11-07|title=[CH₃NH₃]₂Ag₄Sn^IV₂Sn^IIS₈: An Open-Framework Mixed-Valent Chalcogenidostannate|url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.6b02317|journal=Inorganic Chemistry|language=en|volume=55|issue=21|pages=10855–10858|doi=10.1021/acs.inorgchem.6b02317|pmid=27768295|issn=0020-1669|url-access=subscription}}</ref> |- |[CH₃NH₃]₆Ag₁₂Sn₆S₂₁ |monoclinic |''P''2₁/''c'' |''a'' =18.8646 ''b'' =19.9115 ''c'' =14.3125 ''β'' 100.117° | | | |<ref>{{Cite journal|last1=Zhang|first1=Bo|last2=Feng|first2=Mei-Ling|last3=Li|first3=Jun|last4=Hu|first4=Qian-Qian|last5=Qi|first5=Xing-Hui|last6=Huang|first6=Xiao-Ying|date=March 2017|title=Syntheses, Crystal Structures, and Optical and Photocatalytic Properties of Four Small-Amine-Molecule-Directed M–Sn–Q (M = Zn, Ag; Q = S, Se) Compounds|url=https://pubs.acs.org/doi/10.1021/acs.cgd.6b01619|journal=Crystal Growth & Design|language=en|volume=17|issue=3|pages=1235–1244|doi=10.1021/acs.cgd.6b01619|bibcode=2017CrGrD..17.1235Z |issn=1528-7483|url-access=subscription}}</ref> |- |[(Me)₂NH₂]₃[Ag₅Sn₄Se₁₂] |tetragonal |''P''{{overbar|4}}2₁''m'' |a=13.998 c=8.685 Z=2 |1701.9 |4.403 |dark red |<ref>{{Cite journal|last1=Li|first1=Jian-Rong|last2=Huang|first2=Xiao-Ying|date=2011|title=[(Me)₂NH₂]_0.75[Ag_1.25SnSe₃]: A three-dimensionally microporous chalcogenide exhibiting framework flexibility upon ion-exchange|url=http://xlink.rsc.org/?DOI=c0dt01381a|journal=Dalton Transactions|language=en|volume=40|issue=17|pages=4387–4390|doi=10.1039/c0dt01381a|pmid=21225068|issn=1477-9226|url-access=subscription}}</ref> |- |[enH][Cu₂AgSnS₄] | | | | | | |<ref name="CC"/> |- |Cu₂CdSnS₄ | |''I''{{overbar|4}}2''m'' |a=5.402 c=10.86 Z=2 |338 |4.77 | |<ref name="ES"/> |- |Ag₂CdSnS₄ | |''Cmc''2₁ |a=4.111 b=7.038 c=6.685 Z=1 |193 |4.95 | |<ref name="ES"/> |- |Cu₂(Cd,Zn,Fe)SnS₄ Černýite |tetragonal |''I''{{overbar|4}}2''m'' |a = 5.48, c = 10.828 Z=4 |326 |4.76 |metallic |<ref>{{Cite web|title=Černýite|url=https://www.mindat.org/min-1210.html|access-date=2021-07-15|website=www.mindat.org}}</ref> |- |CuInSnS₄ | | |a=10.50 Z=8 |1158 |4.91 | |<ref name="ES"/> |- |AgInSnS₄ | | |a=10.16 Z=8 |1048 |4.59 | |<ref name="ES"/>|<ref name="ES"/> |- |(Cu,Fe,Zn,Ag)₃(Sn,In)S₄ Petrukite |orthorhombic | |a = 7.66, b = 6.43, c = 6.26 |308 | |brown |<ref>{{Cite web|title=Petrukite|url=https://www.mindat.org/min-3178.html|access-date=2021-07-15|website=www.mindat.org}}</ref> |- |(Cu,Zn,Fe)₃(In,Sn)S₄ Sakuraiite |isometric | |a = 5.46 Z=1 |162 | |greenish grey |<ref>{{Cite web|title=Sakuraiite|url=https://www.mindat.org/min-3506.html|access-date=2021-07-15|website=www.mindat.org}}</ref> |- |Sn₂S₃ |orthorhombic |''Pnma'' |a=8.864 b=3.7471 c=14.020 Z=4 |466 |4.76 | |<ref name="ES"/> |- |Cs₄SnS₄ | | | | | |0d |<ref name="shel"/> |- |Cs₂Sn₃S₇ '''·'''0.5S₈ | | | | | |2d |<ref name="shel"/> |- |Cs₄Sn₅S₁₂'''·'''2H₂O | | | | | |2d |<ref name="shel"/> |- |[Cs₄(H₂O)₃][SnS₄] | | | | | | |<ref name="NH"/> |- |Cs₂Sn(S₄)₂(S₆) | | | | | | |<ref name="shel"/> |- |Cs₈Sn₁₀O₄S₂₀'''·'''13H₂O | | | | | | |<ref name="shel"/> |- |[Cs₁₀(H₂O)₁₈][Mn₄(''μ''₄-S)(SnS₄)₄] | | | | | | |<ref name="NH"/> |- |Cs₂ZnSn₃S₈ |monoclinic |''P''2₁/''n'' |''a'' 7.5366 ''b'' 17.6947 ''c'' 12.4976, ''β''=94.830° Z=4 |1660.7 |3.775 |layered, band gap 3. eV |<ref name="tian"/> |- |[Ba₂(H₂O)₁₁][SnS₄] | | | | | | |<ref name="NH"/> |- |Li₂Ba₆MnSn₄S₁₆ |cubic |''I''{{overbar|4}}3''d'' |a=14.6080 Z=4 |3117.3 |4.007 |light yellow |<ref name="SA">{{Cite journal|last1=Duan|first1=Ruihuan|last2=Lin|first2=Hua|last3=Wang|first3=Yue|last4=Zhou|first4=Yuqiao|last5=Wu|first5=Liming|date=2020|title=Non-centrosymmetric sulfides A₂Ba₆MnSn₄S₁₆ (A = Li, Ag): syntheses, structures and properties|url=http://xlink.rsc.org/?DOI=D0DT00894J|journal=Dalton Transactions|language=en|volume=49|issue=18|pages=5914–5920|doi=10.1039/D0DT00894J|pmid=32314776|s2cid=216046852 |issn=1477-9226|url-access=subscription}}</ref> |- |Ag₂Ba₆MnSn₄S₁₆ |cubic |''I''{{overbar|4}}3''d'' |a=14.7064 Z=4 |3180.7 |4.349 |yellow |<ref name="SA"/> |- |Ag₂BaSnS₄ |orthorhombic |''I''222 |''a'' =7.127 ''b'' =8.117 ''c'' =6.854 Z=2 | | |black |<ref>{{Cite journal|last=Teske|first=Chr. L.|date=October 1978|title=Darstellung und Kristallstruktur von Gold-Barium-Thiostannat(lV), Au₂,BaSnS₄|url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.19784450124|journal=Zeitschrift für anorganische und allgemeine Chemie|language=de|volume=445|issue=1|pages=193–201|doi=10.1002/zaac.19784450124|issn=0044-2313|url-access=subscription}}</ref> |- |Ba₃Ag₂Sn₂S₈ | | | | | | |<ref>{{Cite journal|last1=Liu|first1=Yan|last2=Li|first2=Yanhua|last3=Zhao|first3=Jie|last4=Zhang|first4=Renchun|last5=Ji|first5=Min|last6=You|first6=Zhonglu|last7=An|first7=Yonglin|date=January 2020|title=Solvothermal syntheses, characterizations and semiconducting properties of four quaternary thioargentates Ba₂AgInS₄, Ba₃Ag₂Sn₂S₈, BaAg₂MS₄ (M = Sn, Ge)|url=https://linkinghub.elsevier.com/retrieve/pii/S092583881933659X|journal=Journal of Alloys and Compounds|language=en|volume=815|article-number=152413|doi=10.1016/j.jallcom.2019.152413|s2cid=204304414 |url-access=subscription}}</ref> |- |BaSnS₂ | | | | | |Sn(II) |<ref name=":15">{{Cite journal|last1=Sheldrick|first1=William S.|last2=Wachhold|first2=Michael|date=September 1998|title=Chalcogenidometalates of the heavier Group 14 and 15 elements|url=https://linkinghub.elsevier.com/retrieve/pii/S0010854598001209|journal=Coordination Chemistry Reviews|language=en|volume=176|issue=1|pages=211–322|doi=10.1016/S0010-8545(98)00120-9|url-access=subscription}}</ref> |- |BaSn₂S₃ | | | | | |Sn(II) |<ref name=":15"/> |- |BaSnS₃ |orthorhombic |''Pnma'' |a=8.527 b=3.933 c=14.515 Z=4 |487 |4.8 | |<ref name="ES"/> |- |BaSnS₃ |monoclinic |''C''2/''c'' ''Cc'' |a=24.49 b=6.354 c=23.09 ''β''=90.15 Z=28 |3593 |4.55 | |<ref name="ES"/> |- |''α-''Ba₂SnS₄ |monoclinic |''P''2₁/''c'' |a=8.481 b=8.526 c=12.280 ''β''=112.97 Z=4 |818 |4.24 | |<ref name="ES"/> |- |''β-''Ba₂SnS₄ |orthorhombic |''Pnma'' |a=17.823 b=7.359 c=12.613 |1654 |4.18 | |<ref name="ES"/> |- |Ba₃Sn₂S₇ |monoclinic |''P''2₁/''c'' |a=11.073 b=6.771 c=18.703 ''β''=100.77 Z=4 |1378 |4.21 | |<ref name="ES"/> |- |K₂BaSnS₄ | |''R''3''c'' |''a'' 25.419 ''c'' 7.497 | | |band gap 3.09 eV; SHG 0.5×AgGaS₂ |<ref>{{Cite journal|last1=Luo|first1=Xiaoyu|last2=Li|first2=Zhuang|last3=Liang|first3=Fei|last4=Guo|first4=Yangwu|last5=Wu|first5=Yicheng|last6=Lin|first6=Zheshuai|last7=Yao|first7=Jiyong|date=2019-05-20|title=Synthesis, Structure, and Characterization of Two Mixed-Cation Quaternary Chalcogenides K 2 BaSnQ 4 (Q = S, Se)|url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b00967|journal=Inorganic Chemistry|language=en|volume=58|issue=10|pages=7118–7125|doi=10.1021/acs.inorgchem.9b00967|pmid=31067038 |s2cid=148568495 |issn=0020-1669|url-access=subscription}}</ref> |- |Ba₆Cu₂FeSn₄S₁₆ |cubic |''I''{{overbar|4}}3''d'' |a=14.5260 | | |band gap 1.2 eV |<ref name="OP"/> |- |Ba₆Cu₂NiSn₄S₁₆ |cubic |''I''{{overbar|4}}3''d'' |a=14.511 | | |band gap 0.82 eV |<ref name="OP"/> |- |Ba₆Li₂ZnSn₄S₁₆ |cubic |''I''{{overbar|4}}3''d'' |''a''=14.5924 | | | |<ref name=":41">{{Cite journal|last1=Duan|first1=Rui-Huan|last2=Li|first2=Rui-An|last3=Liu|first3=Peng-Fei|last4=Lin|first4=Hua|last5=Wang|first5=Yue|last6=Wu|first6=Li-Ming|date=2018-09-05|title=Modifying Disordered Sites with Rational Cations to Regulate Band-Gaps and Second Harmonic Generation Responses Markedly: Ba₆Li₂ZnSn₄S₁₆ vs Ba₆Ag₂ZnSn₄S₁₆ vs Ba₆Li_2.67Sn_4.33S₁₆|url=https://pubs.acs.org/doi/10.1021/acs.cgd.8b00927|journal=Crystal Growth & Design|language=en|volume=18|issue=9|pages=5609–5616|doi=10.1021/acs.cgd.8b00927|bibcode=2018CrGrD..18.5609D |s2cid=105919832 |issn=1528-7483|url-access=subscription}}</ref> |- |Ba₆Ag₂ZnSn₄S₁₆ |cubic |''I''{{overbar|4}}3''d'' |''a''=14.6839 | | | |<ref name=":41"/> |- |BaCdSnS₄ |orthorhombic |''Fdd''2 |a=21.57 b=21.76 c=13.110 Z=32 |6152 |4.290 |yellow |<ref>{{Cite journal|last1=Zhen|first1=Ni|last2=Wu|first2=Kui|last3=Wang|first3=Ying|last4=Li|first4=Qiang|last5=Gao|first5=Wenhui|last6=Hou|first6=Dianwei|last7=Yang|first7=Zhihua|last8=Jiang|first8=Huaidong|last9=Dong|first9=Yongjun|last10=Pan|first10=Shilie|date=2016|title=BaCdSnS₄ and Ba₃CdSn₂S₈: syntheses, structures, and non-linear optical and photoluminescence properties|url=http://xlink.rsc.org/?DOI=C6DT01537A|journal=Dalton Transactions|language=en|volume=45|issue=26|pages=10681–10688|doi=10.1039/C6DT01537A|pmid=27272926|issn=1477-9226|url-access=subscription}}</ref> |- |Ba₃CdSn₂S₈ |cubic |''I''{{overbar|4}}3''d'' |a=14.723 | | | |<ref name=":11">{{Cite journal|last=Teske|first=Chr. L.|date=1985|title=Darstellung und Kristallstruktur von Ba₃CdSn₂S₈ mit einer Anmerkung über Ba₆CdAg₂Sn₄S₁₆|url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.19855220315|journal=Zeitschrift für anorganische und allgemeine Chemie|language=de|volume=522|issue=3|pages=122–130|doi=10.1002/zaac.19855220315|issn=0044-2313|url-access=subscription}}</ref> |- |Ba₆CdAg₂Sn₄S₁₆ |cubic |''I''{{overbar|4}}3''d'' |a=14.725 | | | |<ref name=":11"/> |- |La₂SnS₅ |orthorhombic |''Pbam'' |a=11.22 b=7.915 c=3.97 Z=2 |352 |5.26 | |<ref name="ES"/> |- |[La(dien)₃]₂[Sn₂S₆]Cl₂ | | | | | |band gap 3.25 eV |<ref>{{Cite journal|last1=Pienack|first1=Nicole|last2=Lühmann|first2=Henning|last3=Näther|first3=Christian|last4=Bensch|first4=Wolfgang|date=January 2016|title=A New Solvothermal Synthetic Route Yields the New Thiostannate [La(dien)₃]₂[Sn₂S₆]Cl₂: The New Thiostannate [La(dien)₃]₂[Sn₂S₆]Cl₂|url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.201500661|journal=Zeitschrift für anorganische und allgemeine Chemie|language=en|volume=642|issue=1|pages=25–30|doi=10.1002/zaac.201500661|url-access=subscription}}</ref> |- |La(peha)(μ–SnS₄H) peha=pentaethylenehexamine |triclinic |''P''{{overbar|1}} |''a'' 8.609 ''b'' 9.327 ''c'' 14.649, ''α'' 79.2° ''β'' 85.5° ''γ'' 63.74° | | | |<ref name=":24">{{Cite journal|last1=Tang|first1=Chunying|last2=Lu|first2=Jialin|last3=Han|first3=Jingyu|last4=Liu|first4=Yun|last5=Shen|first5=Yali|last6=Jia|first6=Dingxian|date=October 2015|title=Complexations of Ln(III) with SnS₄H and Sn₂S₆: Solvothermal syntheses and characterizations of lanthanide coordination polymers with thiostannate and polyamine mixed ligands|url=https://linkinghub.elsevier.com/retrieve/pii/S0022459615300153|journal=Journal of Solid State Chemistry|language=en|volume=230|pages=118–125|doi=10.1016/j.jssc.2015.06.008|bibcode=2015JSSCh.230..118T|url-access=subscription}}</ref> |- |BaCeSn₂S₆ |orthorhombic |''Pmc''2₁ |''a'' 4.0665 ''b'' 19.859 ''c'' 11.873 | | | |<ref name=":40">{{Cite journal|last1=Feng|first1=Kai|last2=Zhang|first2=Xu|last3=Yin|first3=Wenlong|last4=Shi|first4=Youguo|last5=Yao|first5=Jiyong|last6=Wu|first6=Yicheng|date=2014-02-17|title=New Quaternary Rare-Earth Chalcogenides Ba Ln Sn 2 Q 6 ( Ln = Ce, Pr, Nd, Q = S; Ln = Ce, Q = Se): Synthesis, Structure, and Magnetic Properties|url=https://pubs.acs.org/doi/10.1021/ic402934m|journal=Inorganic Chemistry|language=en|volume=53|issue=4|pages=2248–2253|doi=10.1021/ic402934m|pmid=24498849 |issn=0020-1669|url-access=subscription}}</ref> |- |BaPrSn₂S₆ |orthorhombic |''Pmc''2₁ |''a'' 4.0478 ''b'' 19.8914 ''c'' 11.9303 | | | |<ref name=":40"/> |- |BaNdSn₂S₆ |orthorhombic |''Pmc''2₁ |''a'' 4.0098 ''b'' 19.761 ''c'' 11.841 | | | |<ref name=":40"/> |- |[Nd₂(en)₆(μ₂-OH)₂]Sn₂S₆ |monoclinic |''P''2₁/''n'' |''a'' =10.176, ''b'' =11.387, ''c''=15.018, ''β'' =97.869° | | | |<ref name=":4">{{Cite journal|last1=Zhao|first1=Qianxin|last2=Jia|first2=Dingxian|last3=Zhang|first3=Yong|last4=Song|first4=Lifeng|last5=Dai|first5=Jie|date=April 2007|title=First example of thiostannates with lanthanide-containing counter cations: Solvothermal synthesis, crystal structures and properties of thiostannates with neodymium(III) and gadolinium(III) complexes of bidentate and tridentate amino ligands|url=https://linkinghub.elsevier.com/retrieve/pii/S0020169306006463|journal=Inorganica Chimica Acta|language=en|volume=360|issue=6|pages=1895–1901|doi=10.1016/j.ica.2006.09.023|url-access=subscription}}</ref> |- |Nd(peha)(μ–SnS₄H) |triclinic |''P''{{overbar|1}} |''a'' 8.621 ''b'' 9.372 ''c'' 14.656, ''α'' 78.28° ''β'' 84.33° ''γ'' 63.32° | | | |<ref name=":24"/> |- |{Nd(tepa)(μ–OH)}₂(μ–Sn₂S₆)]·H₂O tepa=tetraethylenepentamine |monoclinic |''C''2/''c'' |''a''=21.537 ''b''=12.863 ''c''=17.697 ''β''=124.308° | | | |<ref name=":24"/> |- |[Nd(dien)₃]₂[(Sn₂S₆)Cl₂] dien = diethylenetriamine |monoclinic |''P''2₁/n |''a'' = 11.672, ''b'' = 15.119, ''c'' = 14.157, ''β'' = 96.213°, ''Z'' = 4 |2483.6 | | |<ref name="NT">{{Cite journal|last1=Lu|first1=Xin-hua|last2=Liang|first2=Jing-jing|last3=Zhao|first3=Jing|last4=Zhang|first4=Yong|last5=Jia|first5=Ding-xian|date=April 2011|title=Solvothermal Syntheses and Crystal Structures of Neodymium Thiostannates [Nd(dien)₃]₂[(Sn₂S₆)Cl₂] and [Nd(dien)₃]₂[(Sn₂S₆)(SH)₂]|url=http://link.springer.com/10.1007/s10870-010-9921-5|journal=Journal of Chemical Crystallography|language=en|volume=41|issue=4|pages=557–562|doi=10.1007/s10870-010-9921-5|s2cid=95550419|issn=1074-1542|url-access=subscription}}</ref> |- |[Nd(dien)₃]₂[(Sn₂S₆)(SH)₂] |monoclinic |''P''2₁/n |''a'' = 11.719, ''b'' = 15.217, ''c'' = 14.221, ''β'' = 95.775°, ''Z'' = 4 |2523.1 | | |<ref name="NT"/> |- |(tetaH)₂[Eu₂(teta)₂(tren)₂(μ-Sn₂S₆)]Sn₂S₆ |triclinic |''P''{{overbar|1}} |a=9.886 b=10.371 c=17.442 ''α''=89.78 ''β''=88.00 ''γ=''85.14 Z=1 |1780.8 |1.898 |light yellow |<ref name=":27"/> |- |[Eu₂(tepa)₂(μ-OH)₂(μ-Sn₂S₆)](tepa)_0.5·H₂O tepa = tetraethylene-pentamine |monoclinic |''C''2/''c'' |a=19.803 b=14.998 c=17.800 ''β''=126.57 Z=4 |4246 |1.970 |colourless |<ref name=":27"/> |- |[{Eu(en)₃}₂(μ-OH)₂]Sn₂S₆ |monoclinic |''P''2₁/n |''a'' = 10.116, ''b'' = 11.379, ''c'' = 14.949, ''β'' = 98.209°, Z=2 |1703.1 | | |<ref name="EC">{{Cite journal|last1=Chen|first1=Rui-hong|last2=Wang|first2=Fang|last3=Tang|first3=Chun-ying|last4=Zhang|first4=Yong|last5=Jia|first5=Ding-xian|date=June 2013|title=Solvothermal Syntheses and Crystal Structures of Hexachalcogenidodistannates with Europium Complexes of Different Ethylene Polyamine Ligands|url=http://link.springer.com/10.1007/s10870-013-0423-0|journal=Journal of Chemical Crystallography|language=en|volume=43|issue=6|pages=319–324|doi=10.1007/s10870-013-0423-0|bibcode=2013JCCry..43..319C |s2cid=97917911|issn=1074-1542|url-access=subscription}}</ref> |- |[{Eu(en)₃}₂(μ-OH)₂]Sn₂Se₆ |monoclinic |''P''2₁/n |''a'' = 10.136, ''b'' = 11.771, ''c'' = 15.423, ''β'' = 99.322°, ''Z'' = 2 |1815.8 | | |<ref name="EC"/> |- |[Eu(dien)₃]₂[(Sn₂S₆)(SH)₂] |monoclinic |''P''2₁/n |''a'' = 11.656, ''b'' = 15.168, ''c'' = 14.173, ''β'' = 95.682°, ''Z'' = 2 |2493.4 | | |<ref name="EC"/> |- |(tetaH)₂[Sm₂(teta)₂(tren)₂(μ-Sn₂S₆)]Sn₂S₆ |triclinic |''P''{{overbar|1}} |a=9.920 b=10.382 c=17.520 ''α''=89.91 ''β''=88.07 ''γ=''85.23 Z=1 |1797.1 |1.877 |light yellow |<ref name=":27"/> |- |{Sm(tepa)(μ–OH)}₂(μ–Sn₂S₆)]·H₂O |monoclinic |''C''2/''c'' |''a'' 21.487 ''b'' 12.8199 ''c'' 17.716 ''β'' 124.675° | | | |<ref name=":24"/> |- |[Sm₂(en)₆(''μ'' ₂-OH)₂]Sn₂S₆ |monoclinic |''P''2₁/n |''a'' 10.129 ''b'' 11.377 ''c'' 14.962, ''β'' 98.128° | | | |<ref name="EP">{{Cite journal|last1=Jin|first1=Qinyan|last2=Chen|first2=Jiangfang|last3=Pan|first3=Yingli|last4=Zhang|first4=Yong|last5=Jia|first5=Dingxian|date=2010-05-10|title=Solvothermal syntheses and optical properties of hexathiostannates containing samarium(III) complexes with different ethylene polyamines|url=https://www.tandfonline.com/doi/full/10.1080/00958972.2010.482666|journal=Journal of Coordination Chemistry|language=en|volume=63|issue=9|pages=1492–1503|doi=10.1080/00958972.2010.482666|s2cid=98109293|issn=0095-8972|url-access=subscription}}</ref> |- |[Sm(dien)₃]₂[(Sn₂S₆)Cl₂] |monoclinic |''P''2₁/n |''a'' 11.631 ''b'' 15.091 ''c'' 14.1420 ''β'' 96.202° | | | |<ref name="EP"/> |- |[Sm(dien)₃]₂[(Sn₂S₆)(SH)₂] |monoclinic |''P''2₁/n |''a'' 11.698 ''b'' 15.212 ''c'' 14.219, ''β'' 95.654° | | | |<ref name="EP"/> |- |[Sm(trien)(tren)(Cl)]₂Sn₂S₆ · en |triclinic |''P''{{overbar|1}} |''a'' 10.320 ''b'' 10.491 ''c'' 13.791, ''α'' 100.524° ''β'' 91.930° ''γ'' 119.083° | | | |<ref name="EP"/> |- |{Gd(tepa)(μ–OH)}₂(μ–Sn₂S₆)]·H₂O |monoclinic |''C''2/''c'' |''a'' 21.455 ''b'' 12.804 ''c'' 17.735 ''β'' 124.81° | | | |<ref name=":24"/> |- |[Gd₂(en)₆(μ₂-OH)₂]Sn₂S₆ |monoclinic |''P''2₁/''n'' |''a'' =10.1053 ''b'' =11.357 ''c'' =14.924, ''β'' = 98.346° | | | |<ref name=":4"/> |- |[Gd(dien)₃]₂[(Sn₂S₆)Cl₂] dien = diethylenetriamine |monoclinic |''P''2₁/''n'' |''a'' =11.662, ''b'' =15.168. ''c'' 14.185, ''β'' =95.696° | | | |<ref name=":4"/> |- |{Dy(tepa)(μ–OH)}₂(μ–Sn₂S₆)]·H₂O |monoclinic |''C''2/''c'' |''a'' 21.363 ''b'' 12.717 ''c'' 17.654 ''β'' 124.915° | | | |<ref name=":24"/> |- |[Hen]₂[La(en)₄(CuSn₃S₉)]'''⋅'''0.5 en | | | | | | |<ref name=":26">{{Cite journal|last1=Chen|first1=Ruihong|last2=Wang|first2=Fang|last3=Tang|first3=Chunying|last4=Zhang|first4=Yong|last5=Jia|first5=Dingxian|date=2013-06-17|title=Heterometallic Clusters [CuSn₃S₉]⁵⁻ and [Cu₆Sn₆S₂₀]¹⁰⁻: Solvothermal Synthesis and Characterization of 4f-3d Thiostannates|url=https://onlinelibrary.wiley.com/doi/10.1002/chem.201300044|journal=Chemistry – A European Journal|language=en|volume=19|issue=25|pages=8199–8206|doi=10.1002/chem.201300044|pmid=23616420|url-access=subscription}}</ref> |- |[Hen]₂[Ce(en)₄(CuSn₃S₉)]'''⋅'''0.5 en | | | | | | |<ref name=":26"/> |- |[Hen]₄[Nd(en)₄]₂[Cu₆Sn₆S₂₀]'''⋅'''3 en | | | | | | |<ref name=":26"/> |- |[enH]₄[Sm(en)₄]₂[Cu₆Sn₆S₂₀]·3en |monoclinic |''C''2/''m'' |''a'' 14.257 ''b'' 24.242 ''c'' 13.119 ''β'' 92.223° | | | |<ref name=":36">{{Cite journal|last1=Tan|first1=Xiao-Feng|last2=Liu|first2=Xing|last3=Zhou|first3=Jian|last4=Zhu|first4=Ligang|last5=Zhao|first5=Rongqing|last6=Huang|first6=Qian|date=January 2016|title=Two Quaternary Copper Thiostannates with Lanthanum(III) Complexes|url=http://link.springer.com/10.1007/s10876-015-0927-1|journal=Journal of Cluster Science|language=en|volume=27|issue=1|pages=257–265|doi=10.1007/s10876-015-0927-1|s2cid=93262656|issn=1040-7278|url-access=subscription}}</ref> |- |[Hen]₄[Gd(en)₄]₂[Cu₆Sn₆S₂₀]'''⋅'''3 en | | | | | | |<ref name=":26"/> |- |[enH]₄[Ho(en)₄]₂[Cu₆Sn₆S₂₀]·3en |monoclinic |''C''2/''m'' |''a'' 14.3859 ''b'' 24.361 ''c'' 13.175, ''β'' 93.526° | | | |<ref name=":36"/> |- |EuCu₂SnS₄ |orthorhombic |''Ama''2 |''a''=10.4793, ''b''=10.3610, ''c''=6.4015, ''Z''=4 | | | |<ref>{{Cite journal|last1=Llanos|first1=Jaime|last2=Mujica|first2=Carlos|last3=Sánchez|first3=Vı́ctor|last4=Peña|first4=Octavio|date=June 2003|title=Physical and optical properties of the quaternary sulfides SrCu₂MS₄ and EuCu₂MS₄ (M=Ge and Sn)|url=https://linkinghub.elsevier.com/retrieve/pii/S0022459603000938|journal=Journal of Solid State Chemistry|language=en|volume=173|issue=1|pages=78–82|doi=10.1016/S0022-4596(03)00093-8|bibcode=2003JSSCh.173...78L|url-access=subscription}}</ref><ref>{{Cite journal|last1=Aitken|first1=Jennifer A.|last2=Lekse|first2=Jonathan W.|last3=Yao|first3=Jin-Lei|last4=Quinones|first4=Rosalynn|date=January 2009|title=Synthesis, structure and physicochemical characterization of a noncentrosymmetric, quaternary thiostannate: EuCu₂SnS₄|url=https://linkinghub.elsevier.com/retrieve/pii/S0022459608004945|journal=Journal of Solid State Chemistry|language=en|volume=182|issue=1|pages=141–146|doi=10.1016/j.jssc.2008.09.022|bibcode=2009JSSCh.182..141A|url-access=subscription}}</ref> |- |[Hen]₄[Er(en)₄]₂[Cu₆Sn₆S₂₀]'''⋅'''3 en | | | | | | |<ref name=":26"/> |- |[Hen]₄[Er(en)₄]₂[Ag₆Sn₆S₂₀]·3en |monoclinic |''C''2/''m'' |''a'' 14.557 ''b'' 24.397 ''c'' 13.412 ''β'' 94.42° | | | |<ref name=":22">{{Cite journal|last1=Han|first1=Jingyu|last2=Liu|first2=Yun|last3=Lu|first3=Jialin|last4=Tang|first4=Chunying|last5=Wang|first5=Fang|last6=Shen|first6=Yali|last7=Zhang|first7=Yong|last8=Jia|first8=Dingxian|date=July 2015|title=Heterometallic sulfide cluster [Ag₆Sn₆S₂₀]¹⁰⁻: Solvothermal syntheses and characterizations of silver thiostannates with lanthanide complex counter cations|url=https://linkinghub.elsevier.com/retrieve/pii/S1387700315001707|journal=Inorganic Chemistry Communications|language=en|volume=57|pages=18–21|doi=10.1016/j.inoche.2015.04.018|url-access=subscription}}</ref> |- |[Hen]₄[Tm(en)₄]₂[Ag₆Sn₆S₂₀]·3en |monoclinic |''C''2/''m'' |''a'' 14.517 ''b'' 24.380 ''c'' 13.422 ''β'' 94.46° | | | |<ref name=":22"/> |- |[Hen]₄[Yb(en)₄]₂[Ag₆Sn₆S₂₀]·3en |monoclinic |''C''2/''m'' |''a'' 14.536 ''b'' 24.397 ''c'' 13.397, ''β'' 94.63° | | | |<ref name=":22"/> |- |Cu₆SnWS₈ Kiddcreekite |isometric |''F''{{overbar|4}}3''m'' |a = 10.8178 Z=4 |1265.9 |4.934 |grey |<ref>{{Cite web|title=Kiddcreekite|url=https://www.mindat.org/min-2201.html|access-date=2021-07-15|website=www.mindat.org}}</ref> |- |PtSnS Bowlesite |orthorhombic |''Pca''2₁ |a = 6.12 Å, b = 6.12 Å, c = 6.10 Å Z=4 |228.47 |10.06 |metallic |<ref>{{Cite web|title=Bowlesite|url=https://www.mindat.org/min-54040.html|access-date=2021-07-15|website=www.mindat.org}}</ref> |- |(Pd,Pt)₅(Cu,Fe)₄SnTe₂S₂ Oulankaite |tetragonal | |a = 9.044, c = 4.937 Z=2 |403.8 |10.27 |metallic | |- |K₂Au₂SnS₄ |triclinic |''P''{{overbar|1}} |a=8.212 b=11.019 c=7.314 ''α''=97.82° ''β''=111.72° ''γ''=72.00° Z=2 |483.2 |4.941 |band gap 2.75 eV |<ref name="RI">{{Cite journal|last1=Teske|first1=Christoph Ludwig|last2=Terraschke|first2=Huayna|last3=Mangelsen|first3=Sebastian|last4=Bensch|first4=Wolfgang|date=2020-11-15|title=Re-investigation of Barium-Gold(I)-Tetra-Thiostannate(IV), Ba[Au₂SnS₄], with Short Au^I ···Au^I Separation Showing Luminescence Properties|journal=Zeitschrift für anorganische und allgemeine Chemie|language=en|volume=646|issue=21|pages=1716–1721|doi=10.1002/zaac.202000306|issn=0044-2313|doi-access=free}}</ref><ref name=":13"/> |- |K₂Au₂Sn₂S₆ |tetragonal |''P''4/''mmc'' |a=7.968 c=19.200 Z=4 |1219 |4.914 |band gap 2.30 eV |<ref name="RI"/><ref name=":13"/> |- |Cs₂Au₂SnS₄ |orthorhombic |''Fddd'' |a = 6.143 b = 14.296 c = 24.578 Z = 4 |2158.4 | | |<ref name="RI"/> |- |Ba[Au₂SnS₄] |orthorhombic |C''222''₁ |a=6.6387 b=11.0605 c=10.9676 Z=1 |805.32 |6.418 |red; blue-green luminescent |<ref name="RI"/> |- |K₂Hg₃Sn₂S₈ | | | | | | |<ref>{{Cite journal|last1=Reshak|first1=A.H.|last2=Azam|first2=Sikander|date=November 2014|title=Linear and nonlinear optical properties of α-K₂Hg₃Ge₂S₈ and α-K₂Hg₃Sn₂S₈ compounds|url=https://linkinghub.elsevier.com/retrieve/pii/S0925346714002389|journal=Optical Materials|language=en|volume=37|pages=97–103|doi=10.1016/j.optmat.2014.05.006|bibcode=2014OptMa..37...97R|url-access=subscription}}</ref> |- |Cu₂HgSnS₄ Velikite |tetrahedral |''I''{{overbar|4}}2''m'' |a = 5.55, c = 10.91 |336 |5.450 |dark grey |<ref>{{Cite web|title=Velikite|url=https://www.mindat.org/min-4168.html|access-date=2021-07-08|website=www.mindat.org}}</ref> |- |SrHgSnSe₄ | | | | | | |<ref name=":42">{{Cite journal|last1=Guo|first1=Yangwu|last2=Liang|first2=Fei|last3=Li|first3=Zhuang|last4=Xing|first4=Wenhao|last5=Lin|first5=Zhe-shuai|last6=Yao|first6=Jiyong|last7=Mar|first7=Arthur|last8=Wu|first8=Yicheng|date=2019-08-05|title=AHgSnQ₄ (A = Sr, Ba; Q = S, Se): A Series of Hg-Based Infrared Nonlinear-Optical Materials with Strong Second-Harmonic-Generation Response and Good Phase Matchability|url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b01572|journal=Inorganic Chemistry|language=en|volume=58|issue=15|pages=10390–10398|doi=10.1021/acs.inorgchem.9b01572|pmid=31342744 |s2cid=198494837 |issn=0020-1669|url-access=subscription}}</ref> |- |BaHgSnSe₄ |orthorhombic |''Fdd''2 |''a'' 22.441 ''b'' 22.760 ''c'' 13.579 | | | |<ref name=":42"/> |- |EuHgSnS₄ | |''Ama''2 |''a''=10.3730 ''b''=10.4380 ''c''=6.5680 | | |SHG 1.77×AgGaS₂ |<ref>{{Cite journal|last1=Xing|first1=Wenhao|last2=Tang|first2=Chunlan|last3=Wang|first3=Naizheng|last4=Li|first4=Chunxiao|last5=Li|first5=Zhuang|last6=Wu|first6=Jieyun|last7=Lin|first7=Zheshuai|last8=Yao|first8=Jiyong|last9=Yin|first9=Wenlong|last10=Kang|first10=Bin|date=2020-12-21|title=EuHgGeSe₄ and EuHgSnS₄: Two Quaternary Eu-Based Infrared Nonlinear Optical Materials with Strong Second-Harmonic-Generation Responses|url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c03176|journal=Inorganic Chemistry|language=en|volume=59|issue=24|pages=18452–18460|doi=10.1021/acs.inorgchem.0c03176|pmid=33256399 |s2cid=227245551 |issn=0020-1669|url-access=subscription}}</ref> |- |Tl₄SnS₄ | | | | | |0d | |- |Tl₂SnS₃ | | | | | |1d | |- |Tl₂Sn₂S₅ | | | | | |3d | |- |Tl₄Sn₅S₁₂ | | | | | |3d | |- |PbSnS₂ Teallite |orthorhombic |''Pnma'' |a = 4.26, b = 11.41, c = 4.09 |198.8 |6.36 |metallic | |- |PbSnS₃ Suredaite |orthorhombic |''Pnma'' |a=8.738 b=3.792 c=14.052 Z=4 |466 |6.01 |metallic |<ref name="ES"/> |- |(Pb,Sn)_12.5Sn₅FeAs₃S₂₈ Coiraite |monoclinic | |a = 5.84, b = 5.86, c = 17.32 β = 94.14° Z=4 |591 |5.92 |dark grey |<ref>{{Cite web|title=Coiraite|url=https://www.mindat.org/min-27610.html|access-date=2021-07-15|website=www.mindat.org}}</ref> |- |Fe²⁺(Pb,Sn²⁺)₆Sn⁴⁺₂Sb₂S₁₄ Franckeite |triclinic |''P''{{overbar|1}} |a = 46.9, b = 5.82, c = 17.3 α = 90°, β = 94.66°, γ = 90° Z=8 |4701 |5.90 |black |<ref>{{Cite web|title=Franckeite|url=https://www.mindat.org/min-1592.html|access-date=2021-07-15|website=www.mindat.org}}</ref> |- |Pb_25.7Sn_8.3Mn_3.4Sb_6.4S_56.2 Ramosite |monoclinic | |a = 5.82, b = 5.92, c = 17.65 β = 99.1° |600 | | |<ref>{{Cite web|title=Ramosite|url=https://www.mindat.org/min-54278.html|access-date=2021-07-15|website=www.mindat.org}}</ref> |- |Pb₃Sn₄FeSb₂S₁₄ Cylindrite |triclinic |''P''{{overbar|1}} | | |5.46 |black |<ref>{{Cite web|title=Cylindrite|url=https://www.mindat.org/min-1204.html|access-date=2021-07-15|website=www.mindat.org}}</ref> |- |Pb₆Sn₃FeSb₃S₁₆ Potosíite |triclinic | | | | |grey | |- |(Pb,Ag)₄Sn₄FeSb₂S₁₅ Incaite |monoclinic | | | | | |<ref>{{Cite web|title=Incaite|url=https://www.mindat.org/min-2023.html|access-date=2021-07-15|website=www.mindat.org}}</ref> |- |Pb₂Fe₂Sn₂Sb₂S₁₁ Plumbostannite | | | | | |dark grey |<ref>{{Cite web|title=Plumbostannite|url=https://www.mindat.org/min-29671.html|access-date=2021-07-15|website=www.mindat.org}}</ref> |- |Ba₅Pb₂Sn₃S₁₃ |orthorhombic |''Pnma'' | | | | |<ref>{{Cite journal|last1=Abudurusuli|first1=Ailijiang|last2=Ding|first2=Hanqin|last3=Wu|first3=Kui|date=November 2017|title=Synthesis and characterization of two lead-containing metal chalcogenides: Ba₅Pb₂Sn₃S₁₃ and Ba₆PbSn₃Se₁₃|url=https://linkinghub.elsevier.com/retrieve/pii/S0022459617303262|journal=Journal of Solid State Chemistry|language=en|volume=255|pages=133–138|doi=10.1016/j.jssc.2017.08.019|bibcode=2017JSSCh.255..133A |url-access=subscription}}</ref> |- |Pb₂SnInBiS₇ Abramovite |triclinic |''P''{{overbar|1}} |a = 23.4, b = 5.77, c = 5.83 α = 89.1°, β = 89.9°, γ = 91.5° |786.79 | |metallic |<ref>{{Cite web|title=Abramovite|url=https://www.mindat.org/min-29261.html|access-date=2021-07-15|website=www.mindat.org}}</ref> |- |Pb₈Sn₇Cu₃(Bi,Sb)₃S₂₈ Lévyclaudite |triclinic |''P''{{overbar|1}} | | |5.71 |grey |<ref>{{Cite web|title=Lévyclaudite|url=https://www.mindat.org/min-2387.html|access-date=2021-07-15|website=www.mindat.org}}</ref> |}

== References == {{Reflist}}

{{Sulfides}}

Category:Tin compounds Category:Sulfides