{{Short description|Copper sulfide mineral}} {{Infobox mineral | name = Digenite | category = Sulfide mineral | boxwidth = 24 | boxbgcolor = | image = Digenite.jpg | imagesize = 260px | caption = Digenite from the East Colusa Mine, Butte, Montana, US. Specimen size = 4.3 cm | formula = Cu<sub>9</sub>S<sub>5</sub> | IMAsymbol = Dg<ref>{{Cite journal|last=Warr|first=L.N.|date=2021|title=IMA–CNMNC approved mineral symbols|journal=Mineralogical Magazine|volume=85|issue=3|pages=291–320|doi=10.1180/mgm.2021.43|bibcode=2021MinM...85..291W|s2cid=235729616|doi-access=free}}</ref> | molweight = 146.45 g/mol | strunz = 2.BA.05e | dana = 02.04.07.03 | system = Trigonal | class = Hexagonal scalenohedral ({{overline|3}}m) <br />H-M symbol: ({{overline|3}} 2/m) | symmetry = ''R''{{overline|3}}m | color = Blue to black | habit = Pseudocubic crystals are rare, usually as intergrowths with other copper sulfides | lattice = | twinning = | cleavage = {111} (observed in synthetic material) | fracture = Conchoidal | tenacity = Brittle | mohs = 2.5 to 3 | luster = Submetallic to metallic | refractive = | opticalprop = Reflectivity: 21.6 at 540 nm | birefringence = | pleochroism = | streak = Black | gravity = 5.5 to 5.7 observed, 5.628 calculated | density = | melt = | fusibility = | diagnostic = | solubility = | diaphaneity = Opaque | other = Distinctly blue in polished sections | references = <ref name = Mindat>{{Cite web |url=http://www.mindat.org/min-1291.htm |title=Archived copy |access-date=2010-03-09 |archive-date=2021-02-26 |archive-url=https://web.archive.org/web/20210226225142/http://www.mindat.org/min-1291.htm |url-status=dead }}</ref><ref name = Dana>Gaines et al (1997) Dana's New Mineralogy Eighth Edition, Wiley</ref><ref name=Handbook>http://rruff.geo.arizona.edu/doclib/hom/digenite.pdf Handbook of Mineralogy</ref><ref name=Webmin>http://webmineral.com/data/Digenite.shtml Webmineral data</ref> }}
'''Digenite''' is a copper sulfide mineral with formula: Cu<sub>9</sub>S<sub>5</sub>. Digenite is a black to dark blue opaque mineral that crystallizes with a trigonal–hexagonal scalenohedral structure. In habit it is usually massive, but does often show pseudo-cubic forms. It has poor to indistinct cleavage and a brittle fracture. It has a Mohs hardness of 2.5 to 3 and a specific gravity of 5.6. It is found in copper sulfide deposits of both primary and supergene occurrences. It is typically associated with and often intergrown with chalcocite, covellite, djurleite, bornite, chalcopyrite and pyrite. The type locality is Sangerhausen, Thuringia, Germany, in copper slate deposits.<ref name=Mindat/>
== Occurrence == Digenite occurs in the transitional zone of supergene oxidation of primary sulfide ore deposits, at the interface between the upper and lower saprolite ore zones. It is rarely an important mineral for copper ores, as it is more usually replaced by chalcocite further up in the weathering profile, and is a minor weathering product of primary chalcopyrite. Natural digenite always contains a small amount of iron and is considered to be stable only in the Cu-Fe-S system.<ref name = AM55>American Mineralogist (1970) 55:106</ref>
In the Deflector and Deflector West Cu-Au lode deposits of the Gullewa Greenstone Belt, Western Australia, digenite is an important constituent of the transitional Cu-Au ore. However, it is difficult to treat metallurgically and remains a refractory ore type. In this locality digenite is found with covellite, chalcocite and bornite.
It was first described in 1844 from the type locality of Sangerhausen, Saxony-Anhalt, Germany. The name is from the Greek ''digenus'' meaning of two origins in reference to its close resemblance with chalcocite and covellite.<ref name=Mindat/>
== Polymorphs of digenite ==
There are three polymorphs of digenite, high, metastable and low.<ref name = AM48>American Mineralogist (1963) 48:110</ref> There is a complete solid solution series between high digenite and berzelianite Cu<sub>2−x</sub>Se (x~0.12).<ref name = CM46>Canadian Mineralogist (2008) 46: 219-231</ref>
High digenite is stable above 73 °C, with space group Fm{{overline|3}}m and unit cell parameters a = 5.57 Å and Z = 1 for formula Cu<sub>7.2−x</sub>S<sub>4</sub>. High digenite is isostructural with bornite Cu<sub>5</sub>FeS<sub>4</sub>.<ref name=AM48/>
Metastable digenite forms on cooling from 73 °C. It appears to be isometric with space group Fd{{overline|3}}m and a = 27.85 Å. This symmetry, however, is due to twinning of fine domains with rhombohedral symmetry, trigonal -3m, point group R-3m,<ref name= AM48/> a = 3.92 Å, c = 48 Å, Z = 15 for formula Cu<sub>1.8</sub>S.<ref name=Mindat/> Metastable digenite changes with time to stable low temperature digenite<ref name=AM48/> or a mixture of anilite Cu<sub>7</sub>S<sub>4</sub> and djurleite Cu<sub>31</sub>S<sub>16</sub>.<ref name=AM55/>
Low digenite is isometric, space group Fd{{overline|3}}m and a = 27.85 Å, i.e. the same as the apparent isometric symmetry of the metastable polymorph,<ref name = AM48/> Z=4 for formula Cu<sub>1.8</sub>S.
==References== <references/> * Palache, C., H. Berman, and C. Frondel (1944) ''Dana’s system of mineralogy'', (7th edition), v. I, pp. 180–182.
Category:Sulfide minerals Category:Copper ores Category:Trigonal minerals Category:Minerals in space group 166