{{Short description|Mineral}} {{Infobox mineral | name = Calumetite | image = Calumetite.jpg | alt = | caption = Calumetite from the Akmeek No. 2 Mine in Keweenaw County, Michigan | category = Halide minerals | formula = {{chem|Cu|(OH,Cl)|2|•2(H|2|O)}} | IMAsymbol=Clu<ref>{{Cite journal|last=Warr|first=L.N.|date=2021|title=IMA–CNMNC approved mineral symbols|journal=Mineralogical Magazine|volume=85|issue=3|pages=291–320|doi=10.1180/mgm.2021.43|bibcode=2021MinM...85..291W|s2cid=235729616|doi-access=free}}</ref> | molweight = | strunz = 3.DA.40 | dana = | system = Orthorhombic <br/>Unknown space group | class = | symmetry = | unit cell = | color = | colour = | habit = | twinning = | cleavage = | fracture = | tenacity = | mohs = 2 | luster = | streak = | diaphaneity = | gravity = | density = | polish = | opticalprop = | refractive = | birefringence = | pleochroism = | 2V = | dispersion = | extinction = | length fast/slow = | fluorescence = | absorption = | melt = | fusibility = | diagnostic = | solubility = | impurities = | alteration = | other = | prop1 = | prop1text = | references = <ref>[https://www.mineralienatlas.de/lexikon/index.php/MineralData?mineral=Calumetite Mineralienatlas]</ref> }} '''Calumetite''' is a natural rarely occurring mineral. It was discovered in 1963 at the Centennial Mine near Calumet, Michigan, United States. Calumetite was first discovered along with anthonyite. It has a chemical formula of {{chem|Cu|(OH,Cl)|2|•2(H|2|O)}}.
==History== Calumetite was discovered in 1963 at the Centennial Mine. It is named after the locality where it was found. The Centennial Mine is in Houghton County in Calumet, Michigan. The Centennial Mine has produced other copper minerals. Calumetite has been found to occur in basalt cavities; as painting in canvas and frescos; and also as corrosive products on bronze items. It is found in association with tremolite, quartz, epidote, monazite, copper, cuprite, atacamite, buttgenbachite, malachite, paratacamite, and anthonyite.<ref>Anthony, J.W., Bideaux, R., Bladh, K. and Nichols, M. (2003) Calumetite Cu(OH, Cl)2 •2H2O. Handbook of Mineralogy. Mineral Data Publishing (Republished by the Mineralogical Society of America).</ref> Calumet, the locality where calumetite was found was once considered a mining industry. The Centennial Mine produced approximately 37 million pounds of refined copper before it was closed down in 1966 and overtaken.
==Physical properties== Calumetite occurs as a brilliant azure to powder blue mineral. It has a hardness of 2 with good cleavage along the {001} direction and belongs to the orthorhombic crystal system.
Calumetite has a bluish-white streak. Its luster is pearly on cleavage. Calumetite has a brittle tenacity and is semitransparent.
The specific gravity of calumetite could not be measured because of the difficulty in separating the quartz and epidote from the calumetite mineral coating them.<ref name="ReferenceA">William A. Sidney (1963) Anthonyite and Calumetite, two new minerals from the Michigan Copper District. The American Mineralogist, 48, 614-619</ref>
==Geologic occurrence== Calumetite was discovered with Anthonyite in 1963. Other copper minerals have been linked to calumetite which include copper, cuprite, malachite, atacamite, paratacamite, buttgenbachite.<ref name="ReferenceA"/> The minerals were found in the centennial mine which is known to yield copper minerals. Calumetite has been found in basalt cavities. Calumetite has been stated to be a naturally occurring mineral.<ref>Naumova, M.M., Pisareva S.A (1994) A Note on the Use of Blue and Green Copper Compounds in Paintings. Studies in Conservation, 39, 277-288.</ref> It was prepared with ammonium chloride by means of the lime blue recipe which showed that the mineral is synthetic.<ref>Scott A. David (2000) A Review of Copper Chlorides and Related Salts in Bronze Corrosion and as Painting Pigments. Studies in Conservation, 45, 39-54.</ref> Calumetite was first discovered in calumet Michigan but has since been observed in other mines near the Calumet mine. It was suggested that calumetite is not a post-mine evaporate because of the mode of occurrence{{note|Williams_a}}. Calumetite is insoluble in ammonia and water, and soluble in cold dilute acids.<ref name="ReferenceA"/>
==Chemical properties and uses== Calumetite has been noted to be useful in paintings on canvas and fresco.<ref>Krekel Christopher., Polborn Kurt (2003) Lime Blue: A Mediaeval Pigment for Wall Paintings? Studies in Conservation, 48, 171-182.</ref>
==References== {{Reflist}}
==External links== * [http://webmineral.com/data/Calumetite.shtml Entry on webmineral] * [http://www.mindat.org/min-870.html Entry on mindat] * [http://www.handbookofmineralogy.org/pdfs/CALUMETITE.pdf Handbook of Mineralogy]
Category:Copper(II) minerals Category:Halide minerals Category:Orthorhombic minerals Category:Houghton County, Michigan