# Cleusonite

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{{Short description|Mineral}}
{{Infobox mineral
| name    = Cleusonite
| category = [Oxide minerals](/source/Oxide_minerals)
| formula   = {{chem|(Pb|,Sr)|(U|4+|,U|6+|)(Fe|2+|,Zn)|2|(Ti|,Fe|2+|,Fe|3+|)|18|(O|,OH)|38}}
| IMAsymbol   = Ceu<ref>{{Cite journal|last=Warr|first=L.N.|date=2021|title=IMA–CNMNC approved mineral symbols|journal=Mineralogical Magazine|volume=85|issue=3|pages=291–320|doi=10.1180/mgm.2021.43|bibcode=2021MinM...85..291W|s2cid=235729616|doi-access=free}}</ref>  
| strunz    = 4.CC.40
| system    = [Trigonal](/source/Trigonal)
| class     = Rhombohedral ({{overline|3}}) <br/>[H-M symbol](/source/H-M_symbol): ({{overline|3}})
| symmetry  = ''R''{{overline|3}}
| unit cell = a = 10.385(2)&nbsp;Å, <br/>c = 20.900(7)&nbsp;Å; Z&nbsp;=&nbsp;3
| color     = Black
| habit     = Multiple rhombohedra and hexagonal prisms, [metamict](/source/metamict)
| twinning  = fine twinning
| cleavage  = None
| fracture  = Conchoidal
| tenacity  = Brittle
| mohs      = 6-7
| luster    = Sub metallic
| dispersion = 
| pleochroism = 
| fluorescence= 
| absorption =
| streak   = Black 
| gravity   = 4.74 (synthetic), ~5.15 (calculated)
| solubility = 
| diaphaneity = Opaque
| other = 25px [Radioactive](/source/Radioactive)
| references = <ref name=Webmin>[http://webmineral.com/data/Cleusonite.shtml Webmineral data]</ref><ref name=Mindat>[http://www.mindat.org/min-26262.html Mindat.org]</ref>
}}

'''Cleusonite''' is a member of the [crichtonite](/source/crichtonite) group of minerals with the chemical formula {{chem|(Pb|,Sr)|(U|4+|,U|6+|)(Fe|2+|,Zn)|2|(Ti|,Fe|2+|,Fe|3+|)|18|(O|,OH)|38}}.<ref name=Mindat/>  This group of minerals contains approximately thirteen complex metal titanates. The structures of minerals of this group is complicated by frequent fine-scale [twinning](/source/Crystal_twinning) and [metamictization](/source/metamictization) due to radioactive elements. The crichtonite group consists of members of related mineral species of the type A{BC<sub>2</sub>D<sub>6</sub>E<sub>12</sub>}O<sub>38</sub> which are characterized by their predominant cations (as seen in [crichtonite](/source/crichtonite) (Sr), [senaite](/source/senaite) (Pb), [davidite](/source/davidite) (REE + U), [landauite](/source/landauite) (Na), [loveringite](/source/loveringite) (Ca), [lindsleyite](/source/lindsleyite) (Ba), and [mathiasite](/source/mathiasite) (K).

== Composition ==

The [chemical formula](/source/chemical_formula) of cleusonite is {{chem|(Pb|,Sr)|(U|4+|,U|6+|)(Fe|2+|,Zn)|2|(Ti|,Fe|2+|,Fe|3+|)|18|(O|,OH)|38}}.  The following minerals are also found in the veins of cleusonite; [quartz](/source/quartz), [chlorite](/source/Chlorite_group), [calcite](/source/calcite), [albite](/source/albite), [microcline](/source/microcline), [tourmaline](/source/tourmaline), [fluorapatite](/source/fluorapatite), [zircon](/source/zircon), [ilmenite](/source/ilmenite), [hematite](/source/hematite), [titanite](/source/titanite), [pyrite](/source/pyrite), [chalcopyrite](/source/chalcopyrite), [tennantite](/source/tennantite), [rutile](/source/rutile), [crichtonite](/source/crichtonite), [monazite](/source/monazite)-(Ce), and [native gold](/source/native_gold).

[Clausthalite](/source/Clausthalite), [chalcopyrite](/source/chalcopyrite), and [uraninite](/source/uraninite) are also found in the form of inclusions in cleusonite.

== Structure ==

The structure of the [lead](/source/lead) end-member senaite of the crichtonite group was determined in 1976 by Grey & Lloyd. The structure of the other members of the crichtonite group is similar and corresponds to the formula AM<sub>21</sub>O<sub>38</sub>.

The crystals of cleusonite consist of multiple rhombohedra and hexagonal prisms that are twinned. The [crystal system](/source/crystal_system) is a [trigonal](/source/trigonal) - rhombohedral class 3 and has space group of R{{overline|3}}.

== Physical properties ==
Cleusonite is seen as a black opaque cm-sized tabular crystal with a bright sub-metallic luster. It does not have any cleavage and has a density of about 4.74(4) g/cm3. The calculated density may vary from 5.02(6) (for untreated crystals) to 5.27(5) (heat-treated crystals); the variations are caused by the cell swelling due to the [metamictization](/source/metamictization).

Cleusonite crystals are usually metamict black semimetallic prismatic and associated with [quartz](/source/quartz).

== Geological occurrence characteristics == 
It was found at two occurrences in [greenschist facies](/source/greenschist_facies) metamorphosed [gneiss](/source/gneiss)ic series of the Mont Fort and Siviez-Mischabel Nappes in [Valais](/source/Valais), [Switzerland](/source/Switzerland) (Cleuson and Bella Tolla summit), and named after the [type locality](/source/Type_locality_(geology)). Cleusonite is found first in [metamorphic rock](/source/metamorphic_rock)s of the central Swiss [Alps](/source/Alps) with the type locality being [Oligocene](/source/Oligocene)-[Miocene](/source/Miocene) alpine cleft veins near Cleuson, Val de Nendaz, Valais and secondly in gneisses and crosscutting alpine veins near the Bella Tolla summit, also in Valais. In the Bella Tolla summit it is found in the form of [hematite](/source/hematite)-stained flattened aggregates with [quartz](/source/quartz), [albite](/source/albite), [baryte](/source/baryte), [chalcopyrite](/source/chalcopyrite), [uraninite](/source/uraninite), [tennantite](/source/tennantite), [pyrite](/source/pyrite), [magnetite](/source/magnetite), [cinnabar](/source/cinnabar), and [malachite](/source/malachite). The name cleusonite is used for the previously described “uranium-rich senaite” from [Alinci](/source/Alinci_(Mogila)), [North Macedonia](/source/North_Macedonia) and the "plumbodavidite" from Huanglongpu, [China](/source/China). Cleusonite is [radioactive](/source/radioactive).

== References ==
{{Reflist}}
{{Refbegin}}
* Ercit, S.T et al. (2006). New mineral names. American Mineralogist, 2006; 91; 1201.120.‘Cleusonite Gallery’. (n.d). Retrieved on October 12, 2009. from http://www.mindat.org/gallery.php?min=26262
* Gatehouse, B. M, Grey, I. E, Campbell, I. H & Kelly, P. R. (1978). The crystal structure of loveringite - a new member of the crichtonite group. American Mineralogist, 1978; 63: 28–36.
* General Cleusonite Information (n.d). Retrieved on October 12, 2009, from: http://webmineral.com/data/Cleusonite.shtml 
* Haggerty, S.E et al. (1983). Lindsleyite (Ba) and mathiasite (K): Two new chromium-titanates in the crichtonite series from the upper mantle. American Mineralogist, 1983; 68:494-505.
* Pabst, A. (1961). X-ray crystallography of davidite. American Mineralogist, 1961; 46: 700–718.
* Sabau, G & Alberico, A. (2007). What is CCZN-armalcolite? A crystal-chemical discussion and an ad hoc incursion in the crichtonite-minerals group. Studia Universitatis Babeş-Bolyai, Geologia, 2007; 52 (2); 55–66.
* Wülser, P.A et al. (2005). Cleusonite, (Pb, Sr)(U4+,U6+)(Fe2+,Zn)2(Ti,Fe2+,Fe3+)18(O,OH)38, a new mineral species of the crichtonite group from the western Swiss Alps. European Journal of Mineralogy, 17(6), 933-942 (10). 
* Grey, I.E, Lloyd, D.J & White, J.S. Jr. (1976). The structure of crichtonite and its relationship to senaite. American Mineralogist, 1976; 61: 1203-1212
{{Refend}}

Category:Lead minerals
Category:Strontium minerals
Category:Uranium(IV,VI) minerals
Category:Iron(II,III) minerals
Category:Zinc minerals
Category:Titanium minerals
Category:Oxide minerals
Category:Trigonal minerals
Category:Minerals in space group 148
Category:Minerals described in 2005

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Adapted from the Wikipedia article [Cleusonite](https://en.wikipedia.org/wiki/Cleusonite) by Wikipedia contributors ([contributor history](https://en.wikipedia.org/wiki/Cleusonite?action=history)). Available under [Creative Commons Attribution-ShareAlike 4.0 International](https://creativecommons.org/licenses/by-sa/4.0/). Changes may have been made.
